Fe and Ni co-doped TiO2 nanoparticles prepared by alcohol-thermal method: Application in hydrogen evolution by water splitting under visible light irradiation
文献类型：期刊论文
| 作者 | Sun, Tao1; Fan, Jun1; Liu, Enzhou1; Liu, Lusha1; Wang, Yan1; Dai, Hongzhe1; Yang, Yuhao1; Hou, Wenqian1; Hu, Xiaoyun2; Jiang, Zhenyi3 |
| 刊名 | POWDER TECHNOLOGY
 |
| 出版日期 | 2012-09-01 |
| 卷号 | 228页码:210-218 |
| 关键词 | Fe And Ni Co-doping Alcohol-thermal Method H-2 Evolution Visible Light Irradiation Water Splitting |
| ISSN号 | 0032-5910 |
| DOI | 10.1016/j.powtec.2012.05.018 |
| 文献子类 | Article |
| 英文摘要 | Pure TiO2, single-doped and (Fe. Ni) co-doped TiO2 nanoparticles were successfully prepared by alcohol-thermal method with tetrabutyl titanate as the Ti source. The prepared samples were characterized by Xray powder diffraction (XRD), Brunauer-Emmett-Teller (BET) measurement, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM). UV-visible spectroscopy (UV-vis) and photoluminescence spectroscopy (PL). UV-vis absorption indicates that the co-doped TiO2 exhibits a good absorption of visible light, and the optimal molar ratio of Fe and Ni to Ti is 5.0% and 4.0%, respectively. The photoluminescence spectroscopy indicates that the separation efficiency of photo-induced electrons and holes is improved by the co-doping method. The nano TiO2 samples possess pure anatase phase and doping TiO2 with metal ions can suppress the crystal growth of the particles. The particle sizes of 5.0% Fe-4.0% Ni/TiO2 are about 14 nm. The specific surface area of 5.0% Fe-4.0% Ni co-doped TiO2 is 98.35 m(2)/g while that of the un-doped is 43.13 m(2)/g. The photocatalytic activities of the catalysts were estimated by detecting the H-2 evolution rate from water, and the average maximum H2 evolution rate was 361.64 mu mol.h(-1).g(cat)(-1) (with a measured time of 6 h) using 5.0% Fe-4.0% Ni/TiO2 catalyst. The H-2 evolution rate was detected in the mixture of ethanol and water under visible light irradiation (lambda >400 nm). Additionally, the mechanism of H2 evolution by water splitting is proposed. (C) 2012 Elsevier B.V. All rights reserved. |
| WOS关键词 | AQUEOUS-METHANOL SOLUTION ; PHOTOCATALYTIC ACTIVITY ; CODOPED TIO2 ; SRTIO3 PHOTOCATALYSTS ; HYDROTHERMAL SYNTHESIS ; SOLVOTHERMAL METHOD ; THIN-FILMS ; METAL ; NANOMATERIALS ; DECOMPOSITION |
| 语种 | 英语 |
| WOS记录号 | WOS:000307132300026 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://119.78.100.186/handle/113462/48899]  |
| 专题 | 中国科学院近代物理研究所 |
| 通讯作者 | Fan, Jun |
| 作者单位 | 1.NW Univ Xian, Sch Chem Engn, Xian 710069, Shaanxi, Peoples R China 2.NW Univ Xian, Dept Phys, Xian 710069, Shaanxi, Peoples R China 3.NW Univ Xian, Inst Modern Phys, Xian 710069, Shaanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Tao,Fan, Jun,Liu, Enzhou,et al. Fe and Ni co-doped TiO2 nanoparticles prepared by alcohol-thermal method: Application in hydrogen evolution by water splitting under visible light irradiation[J]. POWDER TECHNOLOGY,2012,228:210-218. |
| APA | Sun, Tao.,Fan, Jun.,Liu, Enzhou.,Liu, Lusha.,Wang, Yan.,...&Jiang, Zhenyi.(2012).Fe and Ni co-doped TiO2 nanoparticles prepared by alcohol-thermal method: Application in hydrogen evolution by water splitting under visible light irradiation.POWDER TECHNOLOGY,228,210-218. |
| MLA | Sun, Tao,et al."Fe and Ni co-doped TiO2 nanoparticles prepared by alcohol-thermal method: Application in hydrogen evolution by water splitting under visible light irradiation".POWDER TECHNOLOGY 228(2012):210-218. |
入库方式： OAI收割
来源：近代物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。