中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Chemical modifications in polyethylene terephthalate films induced by 35 MeV/u Ar ions

文献类型:会议论文

作者Liu, CL; Zhu, ZY; Jin, YF; Sun, YM; Hou, MD; Wang, ZG; Chen, XX; Zhang, CH; Liu, J; Li, BQ
出版日期2000-05
关键词Ar ion irradiation polyethylene terephthalate loss of crystallinity absorbed dose chain scission
卷号166
页码641-645
英文摘要Semicrystalline polyethylene terephthalate (PET) foil stacks were irradiated under vacuum and at room temperature with 35 MeV/u Ar ions to fluences ranging from 1 x 10(10) to 5 x 10(12) ions/cm(2). Ion induced modifications in crystalline and chemical structures were studied by means of differential scanning calorimetry (DSC), Fourier-transform infrared absorption spectroscopy (FTIR), and X-ray diffractometer (XRD). The DSC and XRD data show a significant loss of crystallinity at the absorbed doses higher than 4.0 MGy. FTIR measurements indicate that the loss of crystallinity of the irradiated PET is related to the scission processes of the main chains at the trans configuration of the ethylene glycol residue. Meanwhile, at the absorbed dose above about 4.0 MGy, bond breaking processes at the para position of benzene are also observed. The benzene ring structures are found to be more stable under irradiation. (C) 2000 Elsevier Science B.V. All rights reserved.
会议录NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
会议录出版者ELSEVIER SCIENCE BV
会议录出版地PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
语种英语
WOS研究方向Instruments & Instrumentation ; Nuclear Science & Technology ; Physics
WOS记录号WOS:000087422200113
源URL[http://119.78.100.186/handle/113462/57916]  
专题中国科学院近代物理研究所
通讯作者Liu, CL
作者单位Chinese Acad Sci, Inst Modern Phys, Lanzhou 730000, Peoples R China
推荐引用方式
GB/T 7714
Liu, CL,Zhu, ZY,Jin, YF,et al. Chemical modifications in polyethylene terephthalate films induced by 35 MeV/u Ar ions[C]. 见:.

入库方式: OAI收割

来源:近代物理研究所

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