Chemical modifications in polyethylene terephthalate films induced by 35 MeV/u Ar ions
文献类型:会议论文
作者 | Liu, CL; Zhu, ZY; Jin, YF; Sun, YM; Hou, MD; Wang, ZG; Chen, XX; Zhang, CH; Liu, J; Li, BQ |
出版日期 | 2000-05 |
关键词 | Ar ion irradiation polyethylene terephthalate loss of crystallinity absorbed dose chain scission |
卷号 | 166 |
页码 | 641-645 |
英文摘要 | Semicrystalline polyethylene terephthalate (PET) foil stacks were irradiated under vacuum and at room temperature with 35 MeV/u Ar ions to fluences ranging from 1 x 10(10) to 5 x 10(12) ions/cm(2). Ion induced modifications in crystalline and chemical structures were studied by means of differential scanning calorimetry (DSC), Fourier-transform infrared absorption spectroscopy (FTIR), and X-ray diffractometer (XRD). The DSC and XRD data show a significant loss of crystallinity at the absorbed doses higher than 4.0 MGy. FTIR measurements indicate that the loss of crystallinity of the irradiated PET is related to the scission processes of the main chains at the trans configuration of the ethylene glycol residue. Meanwhile, at the absorbed dose above about 4.0 MGy, bond breaking processes at the para position of benzene are also observed. The benzene ring structures are found to be more stable under irradiation. (C) 2000 Elsevier Science B.V. All rights reserved. |
会议录 | NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS
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会议录出版者 | ELSEVIER SCIENCE BV |
会议录出版地 | PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS |
语种 | 英语 |
WOS研究方向 | Instruments & Instrumentation ; Nuclear Science & Technology ; Physics |
WOS记录号 | WOS:000087422200113 |
源URL | [http://119.78.100.186/handle/113462/57916] ![]() |
专题 | 中国科学院近代物理研究所 |
通讯作者 | Liu, CL |
作者单位 | Chinese Acad Sci, Inst Modern Phys, Lanzhou 730000, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, CL,Zhu, ZY,Jin, YF,et al. Chemical modifications in polyethylene terephthalate films induced by 35 MeV/u Ar ions[C]. 见:. |
入库方式: OAI收割
来源:近代物理研究所
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