Damaging Intermolecular Energy and Proton Transfer Processes in Alpha-Particle-Irradiated Hydrogen-Bonded Systems
文献类型：期刊论文
| 作者 | Xu, Shenyue1,2 ; Guo, Dalong1; Ma, Xinwen1; Zhu, Xiaolong1; Feng, Wentian1; Yan, Shuncheng1; Zhao, Dongmei1; Gao, Yong1; Zhang, Shaofeng1; Ren, Xueguang2,3
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| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2018-12-21 |
| 卷号 | 57页码:17023-17027 |
| ISSN号 | 1433-7851 |
| 关键词 | charged particles energy transfer proton transfer radiation damage |
| DOI | 10.1002/anie.201808898 |
| 英文摘要 | Although the biological hazard of alpha-particle radiation is well-recognized, the molecular mechanisms of biodamage are still far from being understood. Irreparable lesions in biomolecules may not only have mechanical origin but also appear due to various electronic and nuclear relaxation processes of ionized states produced by an alpha-particle impact. Two such processes were identified in the present study by considering an acetylene dimer, a biologically relevant system possessing an intermolecular hydrogen bond. The first process is the already well-established intermolecular Coulombic decay of inner-valence-ionized states. The other is a novel relaxation mechanism of dicationic states involving intermolecular proton transfer. Both processes are very fast and trigger Coulomb explosion of the dimer due to creation of charge-separated states. These processes are general and predicted to occur also in alpha-particle-irradiated nucleobase pairs in DNA molecules. |
| WOS关键词 | ELECTRON MOMENTUM SPECTROSCOPY ; RELAXATION PROCESSES ; COULOMBIC DECAY ; RECOIL-ION ; IONIZATION ; ACETYLENE ; WATER ; PAIRS ; NE |
| 资助项目 | DFG[RE 2966/3-1] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000454575500012 |
| 源URL | [http://119.78.100.186/handle/113462/64478]  |
| 专题 | 中国科学院近代物理研究所 |
| 通讯作者 | Ma, Xinwen; Kryzhevoi, Nikolai, V |
| 作者单位 | 1.Chinese Acad Sci, Inst Modern Phys, Nanchang Rd 509, Lanzhou 730000, Gansu, Peoples R China 2.Xi An Jiao Tong Univ, Sch Sci, Xianning West Rd 28, Xian 710049, Shaanxi, Peoples R China 3.Max Planck Inst Kernphys, Saupfercheckweg 1, D-69117 Heidelberg, Germany 4.Heidelberg Univ, Phys Chem Inst, Theoret Chem, Neuenheimer Feld 229, D-69120 Heidelberg, Germany |
| 推荐引用方式 GB/T 7714 | Xu, Shenyue,Guo, Dalong,Ma, Xinwen,et al. Damaging Intermolecular Energy and Proton Transfer Processes in Alpha-Particle-Irradiated Hydrogen-Bonded Systems[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57:17023-17027. |
| APA | Xu, Shenyue.,Guo, Dalong.,Ma, Xinwen.,Zhu, Xiaolong.,Feng, Wentian.,...&Kryzhevoi, Nikolai, V.(2018).Damaging Intermolecular Energy and Proton Transfer Processes in Alpha-Particle-Irradiated Hydrogen-Bonded Systems.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57,17023-17027. |
| MLA | Xu, Shenyue,et al."Damaging Intermolecular Energy and Proton Transfer Processes in Alpha-Particle-Irradiated Hydrogen-Bonded Systems".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57(2018):17023-17027. |
入库方式： OAI收割
来源：近代物理研究所
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