Highly Efficient and Selective Dissolution Separation of Fission Products by an Ionic Liquid [Hbet][Tf2N]: A New Approach to Spent Nuclear Fuel Recycling
文献类型：期刊论文
| 作者 | Fan, Fang-Li1 ; Qin, Zhi1; Cao, Shi-Wei1; Tan, Cun-Min1; Huang, Qing-Gang1; Chen, De-Sheng1; Wang, Jie-Ru1; Yin, Xiao-Jie1; Xu, Chao2; Feng, Xiao-Gui2
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| 刊名 | INORGANIC CHEMISTRY
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| 出版日期 | 2019-01-07 |
| 卷号 | 58页码:603-609 |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.inorgchem.8b02783 |
| 英文摘要 | Here, we propose the use of carboxyl-functionalized ionic liquid, [Hbet] [Tf2N], to separate the fission products from spent nuclear fuels. This innovative method allows the selective dissolution of neutron poisons, lanthanides oxide, as well as some fission products with high yield, leaving most of the UO2 matrix and minor actinides behind in the spent nuclear fuel and accomplishing the actinides recovery as a group. Water-saturated [Hbet] [Tf2N] can dissolve lanthanides oxide from simulated spent nuclear fuel with a dissolution ratio of 100% at 40 degrees C. However, the dissolution of uranium is almost negligible (<1%) under the same conditions. This big difference in dissolution provides a novel separation approach to spent nuclear fuel recycling and may open new perspectives for spent nuclear fuel reprocessing. The recovery of Nd and U from metal-loaded ionic liquids and the recyclability of the ionic liquid [Hbet] [Tf2N] have also been investigated. Furthermore, a U/x value related to the lattice energy U of metal compound MxOy is used to elaborate the solubility. This work represents the first case for efficient fission products removal by selective dissolution, avoiding the complete dissolution of spent nuclear fuel, the producing of the large high-level radioactive waste, and reducing environmental hazards. |
| WOS关键词 | METAL-COMPLEXES ; ACTINIDES ; LANTHANIDES ; EXTRACTION ; SPECIATION ; BEHAVIOR ; OXIDES ; SURROGATE ; ENERGY ; UO2+X |
| 资助项目 | Natural Sciences Foundation of Gansu Province[17JR5RA298] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000455289000073 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://119.78.100.186/handle/113462/64506]  |
| 专题 | 中国科学院近代物理研究所 |
| 通讯作者 | Qin, Zhi |
| 作者单位 | 1.Chinese Acad Sci, Inst Modern Phys, Lanzhou 730000, Peoples R China 2.Tsinghua Univ, Inst Nucl & New Energy Technol, Nucl Chem & Chem Engn Div, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fan, Fang-Li,Qin, Zhi,Cao, Shi-Wei,et al. Highly Efficient and Selective Dissolution Separation of Fission Products by an Ionic Liquid [Hbet][Tf2N]: A New Approach to Spent Nuclear Fuel Recycling[J]. INORGANIC CHEMISTRY,2019,58:603-609. |
| APA | Fan, Fang-Li.,Qin, Zhi.,Cao, Shi-Wei.,Tan, Cun-Min.,Huang, Qing-Gang.,...&Feng, Xiao-Gui.(2019).Highly Efficient and Selective Dissolution Separation of Fission Products by an Ionic Liquid [Hbet][Tf2N]: A New Approach to Spent Nuclear Fuel Recycling.INORGANIC CHEMISTRY,58,603-609. |
| MLA | Fan, Fang-Li,et al."Highly Efficient and Selective Dissolution Separation of Fission Products by an Ionic Liquid [Hbet][Tf2N]: A New Approach to Spent Nuclear Fuel Recycling".INORGANIC CHEMISTRY 58(2019):603-609. |
入库方式： OAI收割
来源：近代物理研究所
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