Bulk and track etching of PET studied by spectrophotometer
文献类型：期刊论文
| 作者 | Zhu, ZY; Duan, JL; Maekawa, Y; Koshikawa, H; Yoshida, M |
| 刊名 | RADIATION MEASUREMENTS
 |
| 出版日期 | 2004-06-01 |
| 卷号 | 38期号:4页码:255-261 |
| 关键词 | polyethyleneterephthalate bulk and track etching UV light illumination spectrophotometer |
| ISSN号 | 1350-4487 |
| DOI | 10.1016/j.radmeas.2003.12.032 |
| 英文摘要 | UV-VIS spectra of poly(ethylene terephthalate) (PET) solutions formed by etching PET in NaOH solution were analyzed with respect to the etching time. A linear relationship between absorptions centered at 4.45 and 5.11 eV with weight loss of PET in NaOH solution was established. The relation was applied to study the influence of UV light illumination on bulk etching of PET and to evaluate pore size of etched-through tracks. It is found that bulk etching of PET can be greatly enhanced by UV illumination in air in the wavelength range around 313 nm. A surface area of about 350 nm in thickness shows a 23 times increase in bulk-etching rate after illuminated for 6 h. The phenomenon is attributed to the oxygen-assisted photo-degradation through generating of new photo-unstable species. The enhancement in bulk etching was immediately reduced as the etching proceeds below the surface with an exponential decay constant of about 1.5 mum(-1). Etching of Xe ion irradiated PET films gives extra etching products with similar chemical structure as revealed by spectrophotometer measurements. Quantitative analysis of etching products from latent tracks implies that pores of about 14.6 nut in radius are formed after etching in 0.74 N NaOH at 40degreesC for 35 min, which is in agreement with the conductometric measurement. (C) 2003 Elsevier Ltd. All rights reserved. |
| WOS关键词 | POLY(ETHYLENE TEREPHTHALATE) ; PHOTOCHEMICAL DEGRADATION ; ANISOTROPIC ABSORPTION ; CR-39 ; ULTRAVIOLET ; PLASTICS ; DETECTOR ; FILMS ; RATES ; RADIATION |
| WOS研究方向 | Nuclear Science & Technology |
| 语种 | 英语 |
| WOS记录号 | WOS:000220942600001 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 公开日期 | 2010-10-29 |
| 源URL | [http://ir.imp.cas.cn/handle/113462/1209]  |
| 专题 | 近代物理研究所_近代物理研究所知识存储（2010之前） |
| 通讯作者 | Zhu, ZY |
| 作者单位 | 1.Chinese Acad Sci, Inst Modern Phys, Lanzhou 730000, Peoples R China 2.JAERI, Takasaki Radiat Chem Res Establishment, Takasaki, Gumma 3701292, Japan |
| 推荐引用方式 GB/T 7714 | Zhu, ZY,Duan, JL,Maekawa, Y,et al. Bulk and track etching of PET studied by spectrophotometer[J]. RADIATION MEASUREMENTS,2004,38(4):255-261. |
| APA | Zhu, ZY,Duan, JL,Maekawa, Y,Koshikawa, H,&Yoshida, M.(2004).Bulk and track etching of PET studied by spectrophotometer.RADIATION MEASUREMENTS,38(4),255-261. |
| MLA | Zhu, ZY,et al."Bulk and track etching of PET studied by spectrophotometer".RADIATION MEASUREMENTS 38.4(2004):255-261. |
入库方式： OAI收割
来源：近代物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。