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Magnetic characterization of Co1-xNixFe2O4 (0 <= x <= 1) nanoparticles prepared by co-precipitation route

文献类型:期刊论文

作者Maaz, K.1,2; Khalid, W.1; Mumtaz, A.1; Hasanain, S. K.1; Liu, J.3; Duan, J. L.3
刊名PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES
出版日期2009-02-01
卷号41期号:4页码:593-599
关键词Magnetic properties Ferrite nanoparticles Surface anisotropy
ISSN号1386-9477
DOI10.1016/j.physe.2008.10.009
英文摘要Magnetic nanoparticles of Ni-doped cobalt ferrite [Co1-xNixFe2O4(0 <= x <= 1)] synthesized by coprecipitation route have been studied as a function of doping concentration (x) and particle size. The size of the particles as determined by X-ray diffractometer (XRD) and transmission electron microscope (TEM) analyses was found in the range 12-48 nm. The coercivity (H-C) and saturation magnetization (M-S) showed a decreasing behavior with increasing Ni concentration. M-S of all the samples annealed at 600 degrees C lies in the range 65.8-13.7 emu/gm. Field-cooled (FC) studies of the samples showed horizontal shift (exchange bias) and vertical shift in the magnetization loop. Strong decrease in exchange bias (H-b) and vertical shift (delta M) was found for low Ni concentrations while negligible decrease was found at higher concentrations. The presence of exchange bias in the low Ni-concentration region has been explained with reference to the interface spins interaction between a surface region (with structural and spin disorder) and a ferrimagnetic core region. M(T) graphs of the samples showed a decreasing trend of blocking temperature (T-b) with increasing Ni concentration. The decrease of T-b with increasing Ni concentration has been attributed to the lower anisotropy energy of Ni+2 ions as compared to Co+2 that increases the probability of the jump across the anisotropy barrier which in turn decreases the blocking temperature of the system. (C) 2008 Elsevier B.V. All rights reserved.
WOS关键词EXCHANGE BIAS ; COFE2O4 NANOPARTICLES ; NIFE2O4 ; FERRITE ; ANISOTROPY ; POWDERS ; SIZE
资助项目Material Science Group-II, Institute of Modern Physics ; Chinese Academy of Sciences, Lanzhou, PR China
WOS研究方向Science & Technology - Other Topics ; Physics
语种英语
WOS记录号WOS:000264471700015
出版者ELSEVIER SCIENCE BV
资助机构Material Science Group-II, Institute of Modern Physics ; Chinese Academy of Sciences, Lanzhou, PR China
公开日期2010-10-29
源URL[http://ir.imp.cas.cn/handle/113462/5375]  
专题近代物理研究所_近代物理研究所知识存储(2010之前)
通讯作者Maaz, K.
作者单位1.Quaid I Azam Univ, Dept Phys, Islamabad, Pakistan
2.PINSTECH, IAD, Islamabad, Pakistan
3.Chinese Acad Sci, Inst Modern Phys, Lanzhou, Peoples R China
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Maaz, K.,Khalid, W.,Mumtaz, A.,et al. Magnetic characterization of Co1-xNixFe2O4 (0 <= x <= 1) nanoparticles prepared by co-precipitation route[J]. PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES,2009,41(4):593-599.
APA Maaz, K.,Khalid, W.,Mumtaz, A.,Hasanain, S. K.,Liu, J.,&Duan, J. L..(2009).Magnetic characterization of Co1-xNixFe2O4 (0 <= x <= 1) nanoparticles prepared by co-precipitation route.PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES,41(4),593-599.
MLA Maaz, K.,et al."Magnetic characterization of Co1-xNixFe2O4 (0 <= x <= 1) nanoparticles prepared by co-precipitation route".PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES 41.4(2009):593-599.

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来源:近代物理研究所

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