Extraction Behavior of Mo(VI) and W(VI) as Homologs of Sg with -Benzoinoxime
文献类型：期刊论文
| 作者 | Zhang, L. N.2; Fan, F. L.2,3; Lei, F. A.2; Bai, J.2 ; Lin, M. S.2; Li, X. F.2; Ding, H. J.2; Wu, X. L.2; Nayak, D.1; Qin, Z.2
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| 刊名 | SOLVENT EXTRACTION AND ION EXCHANGE
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| 出版日期 | 2009 |
| 卷号 | 27页码:395-407 |
| 关键词 | Molybdenum tungsten -benzoinoxime extraction |
| ISSN号 | 0736-6299 |
| DOI | 10.1080/07366290902821305 |
| 英文摘要 | Solvent extraction of molybdenum and tungsten as homologues of Sg with -benzoinoxime from HCl solutions has been investigated. The extraction equilibration was achieved at 20s for Mo and W. Molybdenum was almost quantitatively extracted from 0.001 to 4M HCl solutions, and the extraction yields decreased at higher and lower acid concentrations due to the formation of anionic oxychloride complex and anionic species MO4 2-, respectively. The extraction yield of W was lower than that of Mo during the whole range of acid concentration. The composition of the extracted species was determined by using the slope method in present experiment. The elemental analysis, IR and 1H NMR spectra of the extracted species suggest that the extracted complex contain one MoO2 2+ or WO2 2+ groups bonded with two -benzoinoxime molecules. |
| WOS关键词 | LIQUID-LIQUID-EXTRACTION ; ALPHA-BENZOINOXIME ; AQUEOUS CHEMISTRY ; ELEMENT 106 ; MO-99 ; MOLYBDENUM(VI) ; SEABORGIUM ; SEPARATION ; HF ; EQUILIBRIUM |
| 资助项目 | National Natural Science Foundation of China[10575122] ; Major State Basic Research Development Program[2007CB 815000] ; Third World Academy of Sciences (TWAS), Trieste, Italy |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000265313500004 |
| 出版者 | TAYLOR & FRANCIS INC |
| 资助机构 | National Natural Science Foundation of China ; Major State Basic Research Development Program ; Third World Academy of Sciences (TWAS), Trieste, Italy |
| 源URL | [http://119.78.100.186/handle/113462/31253]  |
| 专题 | 近代物理研究所_实验物理中心 |
| 通讯作者 | Qin, Z. |
| 作者单位 | 1.Saha Inst Nucl Phys, Div Chem Sci, Kolkata 700064, W Bengal, India 2.Chinese Acad Sci, Inst Modern Phys, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, L. N.,Fan, F. L.,Lei, F. A.,et al. Extraction Behavior of Mo(VI) and W(VI) as Homologs of Sg with -Benzoinoxime[J]. SOLVENT EXTRACTION AND ION EXCHANGE,2009,27:395-407. |
| APA | Zhang, L. N..,Fan, F. L..,Lei, F. A..,Bai, J..,Lin, M. S..,...&Qin, Z..(2009).Extraction Behavior of Mo(VI) and W(VI) as Homologs of Sg with -Benzoinoxime.SOLVENT EXTRACTION AND ION EXCHANGE,27,395-407. |
| MLA | Zhang, L. N.,et al."Extraction Behavior of Mo(VI) and W(VI) as Homologs of Sg with -Benzoinoxime".SOLVENT EXTRACTION AND ION EXCHANGE 27(2009):395-407. |
入库方式： OAI收割
来源：近代物理研究所
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