The Laser-Induced Fluorescence Spectrum of Jet-Cooled Diatomic Sulfur in Ultraviolet Region
文献类型：期刊论文
| 作者 | Ma Xin-wen2 ; Wang Shu-long1,2; Xiang Qian-lan3; Zhao Dong-mei2; Yang Jie2
|
| 刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
 |
| 出版日期 | 2017-09-01 |
| 卷号 | 37页码:2792-2798 |
| 关键词 | Diatomic sulfur molecule Laser-induced fluorescence spectroscopy Low energy excited state Electronic state structure Homogeneous perturbation |
| ISSN号 | 1000-0593 |
| DOI | 10.3964/j.issn.1000-0593(2017)09-2792-07 |
| 英文摘要 | The time-resolved and vibrational emission-resolved laser-induced fluorescence (LIF) spectra of jet -cooled supersonic diatomic sulfur molecule S-2 have been studied in the range of 30 400 similar to 34 400 cm(-1), and 184 bands were observed with high (0.1 cm(-1)) and low (0.3 cm(-1)) resolutions. 84 vibrational transitions were assigned to the B-3 Sigma(-)(u)-X-3 Sigma(-)(g) and B" (3)Pi(u)-X-3 Sigma(-)(g), and the molecular constants in the excited states B-3 Sigma(-)(u)upsilon=0 similar to 9 and B" (3)Pi(u)upsilon=2 similar to 12, including rotational constants, spin -orbit coupling constants, spin-rotation coupling constants, and spin-spin coupling constants, were obtained. The equilibrium molecular geometry in the vibronic ground state of B-3 Sigma(-)(u) was determined by high-resolution spectrum. As there is perturbation between the B-3 Sigma(-)(u) and B'' (3)Pi(u) states of S-2 molecule, the vibrational level intervals, spin-spin coupling constants and spin-orbit coupling constants of B-3 Sigma(-)(u) and B" (3)Pi(u) states are anomalous variation, as well as the intensity of rotational transition and the transition selection rules. The anomalous behavior of the rovibrational spectra was qualitatively explained by the homogeneous perturbations between (3)Sigma-(3)Pi states. |
| WOS关键词 | EXCITATION-SPECTRA |
| WOS研究方向 | Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:000411777800023 |
| 出版者 | OFFICE SPECTROSCOPY & SPECTRAL ANALYSIS |
| 源URL | [http://119.78.100.186/handle/113462/45676]  |
| 专题 | 近代物理研究所_实验物理中心 |
| 通讯作者 | Yang Jie |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 2.Chinese Acad Sci, Inst Modern Phys, Lanzhou 730000, Gansu, Peoples R China 3.Xianyang Normal Univ, Xianyang 712000, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ma Xin-wen,Wang Shu-long,Xiang Qian-lan,et al. The Laser-Induced Fluorescence Spectrum of Jet-Cooled Diatomic Sulfur in Ultraviolet Region[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2017,37:2792-2798. |
| APA | Ma Xin-wen,Wang Shu-long,Xiang Qian-lan,Zhao Dong-mei,&Yang Jie.(2017).The Laser-Induced Fluorescence Spectrum of Jet-Cooled Diatomic Sulfur in Ultraviolet Region.SPECTROSCOPY AND SPECTRAL ANALYSIS,37,2792-2798. |
| MLA | Ma Xin-wen,et al."The Laser-Induced Fluorescence Spectrum of Jet-Cooled Diatomic Sulfur in Ultraviolet Region".SPECTROSCOPY AND SPECTRAL ANALYSIS 37(2017):2792-2798. |
入库方式： OAI收割
来源：近代物理研究所
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