Complex chemistry with complex compounds
文献类型：会议论文
| 作者 | Tanaka, K.2; Eichler, Robert8,9; Brand, H.11; Chiera, N. M.8,9; Di Nitto, A.4,11; Dressler, R.9; Duellmann, Ch. E.4,5,11; Even, J.5,11; Fangli, E.3; Goetz, M.4,5,11 |
| 出版日期 | 2016 |
| 卷号 | 131 |
| DOI | 10.1051/epjconf/201613107005 |
| 英文摘要 | In recent years gas-phase chemical studies assisted by physical pre-separation allowed for the investigation of fragile single molecular species by gas-phase chromatography. The latest success with the heaviest group 6 transactinide seaborgium is highlighted. The formation of a very volatile hexacarbonyl compound Sg(CO)(6) was observed similarly to its lighter homologues molybdenum and tungsten. The interactions of these gaseous carbonyl complex compounds with quartz surfaces were investigated by thermochromatography. Second-generation experiments are under way to investigate the intramolecular bond between the central metal atom of the complexes and the ligands addressing the influence of relativistic effects in the heaviest compounds. Our contribution comprises some aspects of the ongoing challenging experiments as well as an outlook towards other interesting compounds related to volatile complex compounds in the gas phase. |
| 会议录 | NOBEL SYMPOSIUM NS 160 - CHEMISTRY AND PHYSICS OF HEAVY AND SUPERHEAVY ELEMENTS
 |
| 会议录出版者 | E D P SCIENCES |
| 会议录出版地 | 17 AVE DU HOGGAR PARC D ACTIVITES COUTABOEUF BP 112, F-91944 CEDEX A, FRANCE |
| 语种 | 英语 |
| WOS研究方向 | Chemistry ; Physics |
| WOS记录号 | WOS:000392327500029 |
| 源URL | [http://119.78.100.186/handle/113462/57379]  |
| 专题 | 近代物理研究所_实验物理中心 |
| 通讯作者 | Eichler, Robert |
| 作者单位 | 1.Japan Atom Energy Agcy, Adv Sci Res Ctr, Tokai, Ibaraki 3191195, Japan 2.RIKEN, Nishina Ctr Accelerator Based Sci, Wako, Saitama 3510198, Japan 3.Chinese Acad Sci, Inst Modern Phys Lanzhou, Lanzhou 730000, Peoples R China 4.Johannes Gutenberg Univ Mainz, D-55099 Mainz, Germany 5.Helmholtz Inst Mainz, D-55099 Mainz, Germany 6.Kyushu Univ, Higashi Ku, Fukuoka 8128581, Japan 7.Niigata Univ, Niigata, Niigata 9502181, Japan 8.Univ Bern, CH-3012 Bern, Switzerland 9.Paul Scherrer Inst, CH-5232 Villigen, Switzerland 10.Hiroshima Univ, Higashihiroshima 7398526, Japan |
| 推荐引用方式 GB/T 7714 | Tanaka, K.,Eichler, Robert,Brand, H.,et al. Complex chemistry with complex compounds[C]. 见:. |
入库方式： OAI收割
来源：近代物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。