TBAF-Catalyzed O-Nucleophilic Cyclization of Enaminones: A Process for the Synthesis of Dihydroisobenzofuran Derivatives
文献类型：期刊论文
| 作者 | Zhao, Yulei; Zhang, Zheng; Liu, Xu; Wang, Zongkang; Cao, Ziping; Tian, Laijin; Yue, Mingbo; You, Jinmao
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| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
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| 出版日期 | 2019 |
| 卷号 | 84期号:3 |
| 英文摘要 | A novel methodology for the stereoselective synthesis of dihydroisobenzofuran derivatives is described in this paper. The procedure was realized by the bifunctional TBAF catalyzed selective O-nucleophilic cyclization of enaminone with intramolecular alkyne under mild and non-metal-mediated conditions. The results of control experiments suggested that the cation-pi interaction and basicity, offered by TBAF, might be indispensable for the isomerization of enaminone and the formation of carbon-oxygen bond. |
| 源URL | [http://210.75.249.4/handle/363003/59866]  |
| 专题 | 西北高原生物研究所_中国科学院西北高原生物研究所 |
| 推荐引用方式 GB/T 7714 | Zhao, Yulei,Zhang, Zheng,Liu, Xu,et al. TBAF-Catalyzed O-Nucleophilic Cyclization of Enaminones: A Process for the Synthesis of Dihydroisobenzofuran Derivatives[J]. JOURNAL OF ORGANIC CHEMISTRY,2019,84(3). |
| APA | Zhao, Yulei.,Zhang, Zheng.,Liu, Xu.,Wang, Zongkang.,Cao, Ziping.,...&You, Jinmao.(2019).TBAF-Catalyzed O-Nucleophilic Cyclization of Enaminones: A Process for the Synthesis of Dihydroisobenzofuran Derivatives.JOURNAL OF ORGANIC CHEMISTRY,84(3). |
| MLA | Zhao, Yulei,et al."TBAF-Catalyzed O-Nucleophilic Cyclization of Enaminones: A Process for the Synthesis of Dihydroisobenzofuran Derivatives".JOURNAL OF ORGANIC CHEMISTRY 84.3(2019). |
入库方式： OAI收割
来源：西北高原生物研究所
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