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Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst

文献类型：期刊论文

作者Stéphane Streiff1; Feng, Shi2; Hangkong, Yuan2; Bright T. Kusema1; Zhen, Yan1
刊名RSC Advances
出版日期2019-11
卷号9期号:66页码:38877 - 38881
关键词2,5-bis(aminomethyl)furan 5-(hydroxymethyl)furfural bifunctional catalyst CuNiAlOx amination
DOI10.1039/C9RA08560B
英文摘要

The development of facile protocols for the selective synthesis of biomass-derived diamine is a highly desirable pursuit in the field of heterogeneous catalysis. Herein, a simple and highly efficient bi-functional CuNiAlOxcatalyst was developed for the one pot transformation of 5-(hydroxymethyl)furfural (5-HMF) into 2,5-bis(aminomethyl)furan (BAF) using a two-stage reaction process. Cu4Ni1Al4Ox was found to be the most effective catalyst for this reaction, affording BAF in 85.9% yield. Our results could promote controllable conversion and utilization of biomass resource.

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语种英语
源URL[http://ir.licp.cn/handle/362003/25965]  
专题兰州化学物理研究所_OSSO国家重点实验室
通讯作者Feng, Shi; Bright T. Kusema
作者单位1.Eco-Efficient Products and Processes Laboratory (E2P2L), UMI 3464 CNRS-Solvay
2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences
推荐引用方式
GB/T 7714		 Stéphane Streiff,Feng, Shi,Hangkong, Yuan,et al. Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst[J]. RSC Advances,2019,9(66):38877 - 38881.
APA Stéphane Streiff,Feng, Shi,Hangkong, Yuan,Bright T. Kusema,&Zhen, Yan.(2019).Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst.RSC Advances,9(66),38877 - 38881.
MLA Stéphane Streiff,et al."Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH3 over a bifunctional catalyst".RSC Advances 9.66(2019):38877 - 38881.

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来源：兰州化学物理研究所

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