Iron-based metal-organic framework as an effective sorbent for the rapid and efficient removal of illegal dyes
文献类型:期刊论文
作者 | Wang LC(王立成); Lu XF(卢晓锋); Ma JL(马剑龙); Tang H(汤浩); Duo HX(多会晓); Liang XJ(梁晓静) |
刊名 | New Journal of Chemistry |
出版日期 | 2019 |
卷号 | 43期号:38页码:15351-15358 |
关键词 | Metal organic framework Removal Congo red Lemon yellow |
DOI | 10.1039/c9nj03370j |
英文摘要 | A novel metal organic framework (MOF-235) was fabricated by a simple solvothermal method and utilized as an adsorbent for the selective removal of electron-rich conjugated dyes. Parameters that influenced the adsorption process were investigated and the excellent adsorption properties of MOF-235 toward congo red (CR) and lemon yellow (LY) are also exhibited in a wide range of pH 3-9. Moreover, the adsorption kinetic and thermodynamics were determined, indicating that the Langmuir model can well describe adsorption isotherm and the pseudo-second order model can satisfyingly describe adsorption kinetics. Thanks to the large hydrophobic effect between electron-deficient MOF and electron-rich conjugated dye molecules, the ultrahigh maximum adsorption capacity for CR and LY calculated by Langmuir model is up to 1250, 250 mg/g, respectively, which surpasses that of most reported adsorbents. Notably, the maximum adsorption capacity of adsorption CR and LY is up to 1131 and 209 mg/g in the fruit juice, respectively. Additionally, the synthetized MOF-235 has a high adsorptive selectivity, fast adsorption rate and can be regenerated for removal by washing with ethanol containing NaOH solution. These results demonstrated that MOF-235 would be an effective and easily re-usable adsorbent for the adsorptive removal of CR and LY from fruit juice. |
URL标识 | 查看原文 |
语种 | 英语 |
源URL | [http://210.77.64.217/handle/362003/25745] |
专题 | 兰州化学物理研究所_中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 |
通讯作者 | Duo HX(多会晓); Liang XJ(梁晓静) |
作者单位 | 1.University of Chinese Academy of Sciences 2.CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences 3.Department of Pharmacy, Gansu Provincial People’s Hospital |
推荐引用方式 GB/T 7714 | Wang LC,Lu XF,Ma JL,et al. Iron-based metal-organic framework as an effective sorbent for the rapid and efficient removal of illegal dyes[J]. New Journal of Chemistry,2019,43(38):15351-15358. |
APA | Wang LC,Lu XF,Ma JL,Tang H,Duo HX,&Liang XJ.(2019).Iron-based metal-organic framework as an effective sorbent for the rapid and efficient removal of illegal dyes.New Journal of Chemistry,43(38),15351-15358. |
MLA | Wang LC,et al."Iron-based metal-organic framework as an effective sorbent for the rapid and efficient removal of illegal dyes".New Journal of Chemistry 43.38(2019):15351-15358. |
入库方式: OAI收割
来源:兰州化学物理研究所
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