Study of Determination of Phenol Derivatives Based on Ultraviolet Absorption Spectra
文献类型：期刊论文
| 作者 | Juan, YH ; Wu, ZJ ; Chen, LJ |
| 刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
 |
| 出版日期 | 2009 |
| 卷号 | 29期号:8页码:2232-2235 |
| 关键词 | UV absorption spectra Phenol derivative Urease inhibitor |
| ISSN号 | 1000-0593 |
| 通讯作者 | Wu, ZJ, Chinese Acad Sci, Inst Appl Ecol, Shenyang 110016, Peoples R China |
| 中文摘要 | The ultraviolet absorption spectra of phenol and its derivatives were studied under water solution condition. The results show that the introduction of 2-, 3- and 4- substituent of group leads to a bathochromic shift of position of the maximum absorption wavelength lambda(max), and also increases the molar extinction coefficient epsilon(max). However, the extent of influence of substituent of group on lambda(max) and epsilon(max) differs with the introduction position. Compared with 2- and 3- substituent, the 4- substituent induces a bathochromic shift of lambda(max) and the increase of epsilon(max) more greatly, due to the more formation of conjugated structure between 4- substituent of group and benzene ring. The characteristics of 4-nitrophenol's lambda(max) and epsilon(max) supply evidence that nitro is a better auxochrome for phenol derivatives. So UV methods were established for the determination of the contents of phenol derivatives. Using these methods, the adsorptive percentage of four phenol derivatives with epsilon(max)>10 000 was determined, which indicates that phenol derivatives have larger adsorptive percentage in soils with heavy texture, and the solution of inorganic compound with larger concentrations could increase its adsorptive percentage. |
| 学科主题 | Spectroscopy |
| 收录类别 | SCI |
| 语种 | 中文 |
| WOS记录号 | WOS:000269998800049 |
| 公开日期 | 2011-09-23 |
| 源URL | [http://210.72.129.5/handle/321005/54055]  |
| 专题 | 沈阳应用生态研究所_沈阳应用生态研究所_期刊论文 |
| 推荐引用方式 GB/T 7714 | Juan, YH,Wu, ZJ,Chen, LJ. Study of Determination of Phenol Derivatives Based on Ultraviolet Absorption Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2009,29(8):2232-2235. |
| APA | Juan, YH,Wu, ZJ,&Chen, LJ.(2009).Study of Determination of Phenol Derivatives Based on Ultraviolet Absorption Spectra.SPECTROSCOPY AND SPECTRAL ANALYSIS,29(8),2232-2235. |
| MLA | Juan, YH,et al."Study of Determination of Phenol Derivatives Based on Ultraviolet Absorption Spectra".SPECTROSCOPY AND SPECTRAL ANALYSIS 29.8(2009):2232-2235. |
入库方式： OAI收割
来源：沈阳应用生态研究所
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