1,1'-binaphthalene-8,8'-diol as an efficient chiral controller: Highly enantioselective synthesis of optically active ketones
文献类型：期刊论文
| 作者 | Hao, XJ
|
| 刊名 | TETRAHEDRON LETTERS
 |
| 出版日期 | 1996 |
| 卷号 | 37期号:41页码:7373-7376 |
| 关键词 | ONE-STEP SYNTHESIS ESTERS |
| ISSN号 | 0040-4039 |
| 英文摘要 | Half esters (R)-5 of 1,1'-binaphthalene-8,8'-diol undergo 1,4-addition of lithium dialkyl cuprates followed by formal 1,2-addition to give beta-substituted ketones (S)-6 or (S)-7 with high enantioselectivity (96 similar to 100% ee). A brief discussion of the mechanism is presented. Copyright (C) 1996 Elsevier Science Ltd |
| 学科主题 | Chemistry, Organic |
| 收录类别 | SCI |
| 语种 | 英语 |
| 公开日期 | 2012-03-21 |
| 源URL | [http://ir.kib.ac.cn/handle/151853/4344]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Hao, XJ. 1,1'-binaphthalene-8,8'-diol as an efficient chiral controller: Highly enantioselective synthesis of optically active ketones[J]. TETRAHEDRON LETTERS,1996,37(41):7373-7376. |
| APA | Hao, XJ.(1996).1,1'-binaphthalene-8,8'-diol as an efficient chiral controller: Highly enantioselective synthesis of optically active ketones.TETRAHEDRON LETTERS,37(41),7373-7376. |
| MLA | Hao, XJ."1,1'-binaphthalene-8,8'-diol as an efficient chiral controller: Highly enantioselective synthesis of optically active ketones".TETRAHEDRON LETTERS 37.41(1996):7373-7376. |
入库方式： OAI收割
来源：昆明植物研究所
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