A Fragmentation Study of Kaempferide 3,7-Di-O-glycosides by Electrospray Ionization Tandem Mass Spectrometry
文献类型:期刊论文
作者 | Lu L ; Shi Y ; Song FR ; Jin YR ; Liu ZQ ; Liu SY |
刊名 | acta chimica sinica
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出版日期 | 2010 |
卷号 | 68期号:17页码:1735-1740 |
关键词 | COLLISION-INDUCED DISSOCIATION FLAVONOID GLYCOSIDES CLEAVAGE AGLYCONES |
ISSN号 | 0567-7351 |
通讯作者 | lu l |
中文摘要 | a serious of new methoxylated flavonol including kaempferide mono-o-glycosides and kaempferide 3,7-di-o-glycosides from actinidia kolomikta were studied by using electrospray ionization tandem mass spectrometry. the results indicated kaempferide mono-o and di-o have substantial difference in their fragmentation behaviors. kaempferide mono-o-glycosides yielded abundant aglycone ion ([y-0](-)) by loss of glycan residues, however, 3,7-di-o-glycosides mostly generated [y-0(3)](-) and [y-0(7)](-) ions through removal of glycan residues substituted in c-7 and c-7 respectively, but little aglycone ion from loss of all substituted glycans. furthermore, the glycosylation site could be easily determined because the [y-0(3)](-) and [y-0(7)](-) ions shown different fragmentation pathways. |
收录类别 | SCI收录期刊论文 |
语种 | 中文 |
WOS记录号 | WOS:000284511400011 |
公开日期 | 2012-04-25 |
源URL | [http://ir.ciac.jl.cn/handle/322003/43260] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Lu L,Shi Y,Song FR,et al. A Fragmentation Study of Kaempferide 3,7-Di-O-glycosides by Electrospray Ionization Tandem Mass Spectrometry[J]. acta chimica sinica,2010,68(17):1735-1740. |
APA | Lu L,Shi Y,Song FR,Jin YR,Liu ZQ,&Liu SY.(2010).A Fragmentation Study of Kaempferide 3,7-Di-O-glycosides by Electrospray Ionization Tandem Mass Spectrometry.acta chimica sinica,68(17),1735-1740. |
MLA | Lu L,et al."A Fragmentation Study of Kaempferide 3,7-Di-O-glycosides by Electrospray Ionization Tandem Mass Spectrometry".acta chimica sinica 68.17(2010):1735-1740. |
入库方式: OAI收割
来源:长春应用化学研究所
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