Electrophosphorescent Heterobimetallic Oligometallaynes and Their Applications in Solution-Processed Organic Light-Emitting Devices
文献类型：期刊论文
| 作者 | Zhou GJ ; He Y ; Yao B ; Dang JS ; Wong WY ; Xie ZY ; Zhao XA ; Wang LX |
| 刊名 | chemistry-an asian journal
 |
| 出版日期 | 2010 |
| 卷号 | 5期号:11页码:2405-2414 |
| 关键词 | CYCLOMETALATED IRIDIUM COMPLEXES EFFECTIVE CORE POTENTIALS SATURATED RED EMISSION SENSITIZED SOLAR-CELLS ELECTROLUMINESCENT DEVICES HIGH-EFFICIENCY PHOSPHORESCENT MATERIALS PLATINUM(II) COMPLEXES EXCITED-STATE PHOTOPHYSICAL CHARACTERIZATION |
| ISSN号 | 1861-4728 |
| 通讯作者 | zhou gj |
| 中文摘要 | by combining the iridium-(iii) ppy-type complex (hppy = 2-phenylpyridine) with a square-planar platinum(ii) unit, some novel phosphorescent oligometallaynes bearing dual metal centers (viz. ir-iii and pt-ii) were developed by combining trans-[pt-(pbu3)(2)cl-2] with metalloligands of iridium possessing bifunctional pendant acetylene groups. photophysical and computational studies indicated that the phosphorescent excited states arising from these oligometallaynes can be ascribed to the triplet emissive ir-iii ppy-type chromophore, owing to the obvious trait (such as the longer phosphorescent lifetime at 77 k) also conferred by the pt-iii center. so, the two different metal centers show a synergistic effect in governing the photophysical behavior of these heterometallic oligometallaynes. the inherent nature of these amorphous materials renders the fabrication of simple solution-processed doped phosphorescent organic light-emitting diodes (pholeds) feasible by effectively blocking the close-packing of the host molecules. saliently, such a synergistic effect is also important in affording decent device performance for the solution-processed pholeds. a maximum brightness of 3356 cd m(-2) (or 2708 cd m(-2)), external quantum efficiency of 0.50% (or 0.67%), luminance efficiency of 1.59 cd a(-1) (or 1.55 cd a(-1)), and power efficiency of 0.60 lm w-1 (or 0.55 lm w-1) for the yellow (or orange) phosphorescent pholeds can be obtained. these results show the great potential of these bimetallic emitters for organic light-emitting diodes. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000284515100013 |
| 公开日期 | 2012-04-25 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43278]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhou GJ,He Y,Yao B,et al. Electrophosphorescent Heterobimetallic Oligometallaynes and Their Applications in Solution-Processed Organic Light-Emitting Devices[J]. chemistry-an asian journal,2010,5(11):2405-2414. |
| APA | Zhou GJ.,He Y.,Yao B.,Dang JS.,Wong WY.,...&Wang LX.(2010).Electrophosphorescent Heterobimetallic Oligometallaynes and Their Applications in Solution-Processed Organic Light-Emitting Devices.chemistry-an asian journal,5(11),2405-2414. |
| MLA | Zhou GJ,et al."Electrophosphorescent Heterobimetallic Oligometallaynes and Their Applications in Solution-Processed Organic Light-Emitting Devices".chemistry-an asian journal 5.11(2010):2405-2414. |
入库方式： OAI收割
来源：长春应用化学研究所
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