Phosphonate-Functionalized Polyfluorene Film Sensors for Sensitive Detection of Iron(III) in both Organic and Aqueous Media
文献类型：期刊论文
| 作者 | Wu XF ; Xu BW ; Tong H ; Wang LX |
| 刊名 | macromolecules
 |
| 出版日期 | 2010 |
| 卷号 | 43期号:21页码:8917-8923 |
| 关键词 | SELF-ASSEMBLED MONOLAYERS FLUORESCENT CONJUGATED POLYMERS III-AMPLIFIED FLUORESCENCE SILICON-OXIDE SURFACES CHEMICAL SENSORS ION RECOGNITION SIDE-CHAINS METAL-IONS THIN-FILM CHEMOSENSORS |
| ISSN号 | 0024-9297 |
| 通讯作者 | tong h |
| 中文摘要 | a novel conjugated polymer (cp) based thin film sensor toward fe3+ was prepared by covalent immobilization of a phosphonate-functionalized polyfluorene on glass surface. contact angle, xps and steady-state fluorescence measurements proved that the polyfluorene was successfully chemically conjugated on the substrate surface. like the organic solution and spin-casting film of this polyfluorene, the fluorescence of the immobilized film can be selectively quenched by fe3+ in both organic and aqueous solutions. limit of detection of this film sensor for fe3+ could be down to 8.4 ppb in thf solution and 0.14 ppm in aqueous solution, which were among the best results for fe3+ sensing by fluorescence film sensors reported so far. compared with the fluorescence quenching properties of the same polyfluorene in thf solution and in spin-casting film, both quenching constant and detection limit of the immobilized film were improved by i order of magnitude, which demonstrated the advantage of the immobilized film fluorescence sensor. in addition, the sensing process is reversible in both organic and aqueous solutions. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000283693500030 |
| 公开日期 | 2012-04-25 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43290]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wu XF,Xu BW,Tong H,et al. Phosphonate-Functionalized Polyfluorene Film Sensors for Sensitive Detection of Iron(III) in both Organic and Aqueous Media[J]. macromolecules,2010,43(21):8917-8923. |
| APA | Wu XF,Xu BW,Tong H,&Wang LX.(2010).Phosphonate-Functionalized Polyfluorene Film Sensors for Sensitive Detection of Iron(III) in both Organic and Aqueous Media.macromolecules,43(21),8917-8923. |
| MLA | Wu XF,et al."Phosphonate-Functionalized Polyfluorene Film Sensors for Sensitive Detection of Iron(III) in both Organic and Aqueous Media".macromolecules 43.21(2010):8917-8923. |
入库方式： OAI收割
来源：长春应用化学研究所
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