Copper(0)-Mediated Living Radical Polymerization of Acrylonitrile: SET-LRP or AGET-ATRP
文献类型：期刊论文
| 作者 | Liu XH ; Zhang GB ; Li BX ; Bai YG ; Li YS |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 2010 |
| 卷号 | 48期号:23页码:5439-5445 |
| 关键词 | FRAGMENTATION CHAIN TRANSFER HIGHER-MOLECULAR-WEIGHT ELECTRON-TRANSFER METHYL ACRYLATE 25-DEGREES-C KINETICS COPOLYMERS POLYMERS DMSO |
| ISSN号 | 0887-624x |
| 通讯作者 | li ys |
| 中文摘要 | cu(0)-mediated living radical polymerization was first extended to acrylonitrile (an) to synthesize polyacrylonitrile with a high molecular weight and a low polydispersity index. this was achieved by using cu(0)/hexamethylated tris(2-amino-ethyl)amine (me-6-tren) as the catalyst, 2-bromopropionitrile as the initiator, and dimethyl sulfoxide (dmso) as the solvent. the reaction was performed under mild reaction conditions at ambient temperature and thus biradical termination reaction was low. the rapid and extensive disproportionation of cu(i)br/me-6-tren in dmso/an supports a mechanism consistent with a single electron transfer-living radical polymerization (set-lrp) rather than activators generated by electron transfer atom transfer radical polymerization (aget atrp). h-1 nmr analysis and chain extension experiment confirm the high chain-end functionality of the resultant polymer. (c) 2010 wiley periodicals, inc. j polym sci part a: polym chem 48: 5439-5445, 2010 |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000284225500020 |
| 公开日期 | 2012-04-25 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43297]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu XH,Zhang GB,Li BX,et al. Copper(0)-Mediated Living Radical Polymerization of Acrylonitrile: SET-LRP or AGET-ATRP[J]. journal of polymer science part a-polymer chemistry,2010,48(23):5439-5445. |
| APA | Liu XH,Zhang GB,Li BX,Bai YG,&Li YS.(2010).Copper(0)-Mediated Living Radical Polymerization of Acrylonitrile: SET-LRP or AGET-ATRP.journal of polymer science part a-polymer chemistry,48(23),5439-5445. |
| MLA | Liu XH,et al."Copper(0)-Mediated Living Radical Polymerization of Acrylonitrile: SET-LRP or AGET-ATRP".journal of polymer science part a-polymer chemistry 48.23(2010):5439-5445. |
入库方式： OAI收割
来源：长春应用化学研究所
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