Transfer hydrogenation of citral to citronellol with Ru complexes in the mixed solvent of water and polyethylene glycol
文献类型：期刊论文
| 作者 | Cheng HY ; Liu RX ; Hao JM ; Wang QA ; Yu YC ; Cai SX ; Zhao FY |
| 刊名 | applied organometallic chemistry
 |
| 出版日期 | 2010 |
| 卷号 | 24期号:11页码:763-766 |
| 关键词 | ASYMMETRIC TRANSFER HYDROGENATION SUPERCRITICAL CARBON-DIOXIDE CHEMOSELECTIVE TRANSFER HYDROGENATION BIPHASIC TRANSFER HYDROGENATION POLY(ETHYLENE GLYCOL) UNSATURATED ALDEHYDES ORGANOMETALLIC CATALYSIS PALLADIUM NANOPARTICLES RUTHENIUM COMPLEXES AEROBIC OXIDATION |
| ISSN号 | 0268-2605 |
| 通讯作者 | zhao fy |
| 中文摘要 | the transfer hydrogenation of citral to citronellol was studied with [rucl2(benzene)](2) catalyst in a mixed solvent of water and polyethylene glycol (h2o-peg). the influence of several important factors including hydrogen source, solvent, temperature and active species is discussed. under the present conditions, citronellol was produced with an extremely high selectivity above 90%. the ru complexes could be immobilized in the h2o-peg phase well and separated from organic products successfully. moreover, a stable catalytic activity was obtained after the first run, although the decomposition of ru complexes occurred during the recycling processes. the selectivity to citronellol decreased but kept a stable level about 60% in the recycling runs. copyright (c) 2010 john wiley & sons, ltd. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000283977900003 |
| 公开日期 | 2012-04-25 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43309]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Cheng HY,Liu RX,Hao JM,et al. Transfer hydrogenation of citral to citronellol with Ru complexes in the mixed solvent of water and polyethylene glycol[J]. applied organometallic chemistry,2010,24(11):763-766. |
| APA | Cheng HY.,Liu RX.,Hao JM.,Wang QA.,Yu YC.,...&Zhao FY.(2010).Transfer hydrogenation of citral to citronellol with Ru complexes in the mixed solvent of water and polyethylene glycol.applied organometallic chemistry,24(11),763-766. |
| MLA | Cheng HY,et al."Transfer hydrogenation of citral to citronellol with Ru complexes in the mixed solvent of water and polyethylene glycol".applied organometallic chemistry 24.11(2010):763-766. |
入库方式： OAI收割
来源：长春应用化学研究所
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