The Preparation of Malefic Anhydride Modified Polyethylene via in-situ Chlorinating Graft Copolymerization
文献类型:期刊论文
作者 | Ma YQ ; Zhang L ; Du ZA ; Zhao JR ; Feng Y ; Yin JH |
刊名 | polymer-plastics technology and engineering
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出版日期 | 2010 |
卷号 | 49期号:1页码:24-31 |
关键词 | ATACTIC POLYPROPYLENE MALEIC-ANHYDRIDE COMPATIBILIZER MELT |
ISSN号 | 0360-2559 |
通讯作者 | zhao jr |
中文摘要 | a graft copolymer, composed of malefic anhydride as side group and high-density polyethylene as backbone, was synthesized by a new method, in-situ chlorinating graft copolymerization. the result of fourier transform infrared scans indicated the existence of anhydride polyethylene even if the chlorine content of the products was low (about 3%). reactive degree of anhydridisation of polyethylene (ad), which was up to 1.4 wt%, was measured by chemical titration. the crystal behavior of graft copolymer was characterized by x-ray diffraction and differential scanning calorimetry. the results of gel content and viscosity average molecular weight showed the modified polyethylene had no cross-link and degradation. scanning electron microscope indicated that the compatibility between graft copolymer and polar polymers, such as poly (vinyl chloride), increased greatly compared with high-density polyethylene. as is highlighted in this paper, the preparation of anhydride polyethylene could be carried out efficiently and simply via in-situ chlorinating graft copolymerization. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000283073700005 |
公开日期 | 2012-04-25 |
源URL | [http://ir.ciac.jl.cn/handle/322003/43331] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Ma YQ,Zhang L,Du ZA,et al. The Preparation of Malefic Anhydride Modified Polyethylene via in-situ Chlorinating Graft Copolymerization[J]. polymer-plastics technology and engineering,2010,49(1):24-31. |
APA | Ma YQ,Zhang L,Du ZA,Zhao JR,Feng Y,&Yin JH.(2010).The Preparation of Malefic Anhydride Modified Polyethylene via in-situ Chlorinating Graft Copolymerization.polymer-plastics technology and engineering,49(1),24-31. |
MLA | Ma YQ,et al."The Preparation of Malefic Anhydride Modified Polyethylene via in-situ Chlorinating Graft Copolymerization".polymer-plastics technology and engineering 49.1(2010):24-31. |
入库方式: OAI收割
来源:长春应用化学研究所
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