Preparation of one dimensional group 14 metal sulfides: different roles of metal-amino complexes
文献类型:期刊论文
作者 | Wang ZQ ; Xu GF ; Bi YF ; Wang C |
刊名 | crystengcomm
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出版日期 | 2010 |
卷号 | 12期号:11页码:3703-3707 |
关键词 | TRANSITION-METAL SOLVOTHERMAL SYNTHESIS CRYSTAL-STRUCTURE ANION CHALCOGENIDES EXAMPLE CHAINS ZN CO ETHYLENEDIAMINE |
ISSN号 | 1466-8033 |
通讯作者 | wang c |
中文摘要 | two organic-inorganic hybrid one dimensional (1d) sulfides [mn(en)(2)(h2o)][mn(en)(2)mnge3s9] (1) and [mn(en)(2)](2)sn2s6 (2) (en = ethylenediamine) have been prepared under solvothermal conditions and characterized by single-crystal x-ray diffraction. metal-amino complexes play different roles in preparing these two compounds: in 1, [mn(en)(2)](2+) cations decorate the chains constructed by ternary t-2[mnge3s10](6-) clusters through their non-terminal s atoms, and [mn(en)(2)(h2o)](2+) cations act as templates. while in 2, [mn(en)(2)](2+) cations and [sn2s6](4-) dimeric anions are bridged together in an alternative manner to form its chain-like structure. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000283315900065 |
公开日期 | 2012-04-25 |
源URL | [http://ir.ciac.jl.cn/handle/322003/43341] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Wang ZQ,Xu GF,Bi YF,et al. Preparation of one dimensional group 14 metal sulfides: different roles of metal-amino complexes[J]. crystengcomm,2010,12(11):3703-3707. |
APA | Wang ZQ,Xu GF,Bi YF,&Wang C.(2010).Preparation of one dimensional group 14 metal sulfides: different roles of metal-amino complexes.crystengcomm,12(11),3703-3707. |
MLA | Wang ZQ,et al."Preparation of one dimensional group 14 metal sulfides: different roles of metal-amino complexes".crystengcomm 12.11(2010):3703-3707. |
入库方式: OAI收割
来源:长春应用化学研究所
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