中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Preparation of one dimensional group 14 metal sulfides: different roles of metal-amino complexes

文献类型:期刊论文

作者Wang ZQ ; Xu GF ; Bi YF ; Wang C
刊名crystengcomm
出版日期2010
卷号12期号:11页码:3703-3707
关键词TRANSITION-METAL SOLVOTHERMAL SYNTHESIS CRYSTAL-STRUCTURE ANION CHALCOGENIDES EXAMPLE CHAINS ZN CO ETHYLENEDIAMINE
ISSN号1466-8033
通讯作者wang c
中文摘要two organic-inorganic hybrid one dimensional (1d) sulfides [mn(en)(2)(h2o)][mn(en)(2)mnge3s9] (1) and [mn(en)(2)](2)sn2s6 (2) (en = ethylenediamine) have been prepared under solvothermal conditions and characterized by single-crystal x-ray diffraction. metal-amino complexes play different roles in preparing these two compounds: in 1, [mn(en)(2)](2+) cations decorate the chains constructed by ternary t-2[mnge3s10](6-) clusters through their non-terminal s atoms, and [mn(en)(2)(h2o)](2+) cations act as templates. while in 2, [mn(en)(2)](2+) cations and [sn2s6](4-) dimeric anions are bridged together in an alternative manner to form its chain-like structure.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000283315900065
公开日期2012-04-25
源URL[http://ir.ciac.jl.cn/handle/322003/43341]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Wang ZQ,Xu GF,Bi YF,et al. Preparation of one dimensional group 14 metal sulfides: different roles of metal-amino complexes[J]. crystengcomm,2010,12(11):3703-3707.
APA Wang ZQ,Xu GF,Bi YF,&Wang C.(2010).Preparation of one dimensional group 14 metal sulfides: different roles of metal-amino complexes.crystengcomm,12(11),3703-3707.
MLA Wang ZQ,et al."Preparation of one dimensional group 14 metal sulfides: different roles of metal-amino complexes".crystengcomm 12.11(2010):3703-3707.

入库方式: OAI收割

来源:长春应用化学研究所

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