Fabrication and photoluminescence properties of hollow Gd2O3:Ln (Ln = Eu3+, Sm3+) spheres via a sacrificial template method
文献类型：期刊论文
| 作者 | Liu YC ; Yang PP ; Wang WX ; Dong HX ; Lin J |
| 刊名 | crystengcomm
 |
| 出版日期 | 2010 |
| 卷号 | 12期号:11页码:3717-3723 |
| 关键词 | COLLOIDAL CARBON SPHERES CORE-SHELL STRUCTURE HYDROTHERMAL SYNTHESIS LUMINESCENT PROPERTIES PHOSPHOR PARTICLES TITANIA SPHERES SILICA SPHERES AEROSOL ROUTE NANOPARTICLES OXIDE |
| ISSN号 | 1466-8033 |
| 通讯作者 | yang pp |
| 中文摘要 | hollow gd2o3:ln (ln = eu3+, sm3+) microspheres were successfully fabricated by using carbon spheres as a template and urea as a precipitating agent, which involved the deposition of an inorganic coating on the surface of carbon spheres and subsequent calcination in the air. various approaches including x-ray diffraction (xrd), scanning electron microscopy (sem), transmission electron microscopy (tem), fourier transform infrared (ft-ir), thermogravimetric and differential thermal analysis (tg-dta), photoluminescence spectroscopy as well as kinetic decays were used to characterize the samples. the results indicate that the as-prepared products can be indexed to pure cubic gd2o3 phase. the samples are composed of uniform hollow gd2o3:ln spheres with a mean particle size of about 300 nm. the possible mechanism of evolution from glucose to carbon microspheres and the chemical reaction of each step to form the final hollow spheres are proposed. in particular, the urea-assisted precipitation process was carried out in aqueous solution without any organic solvent, and the hollow spheres formation process was achieved by simple calcination without using any etching agents. the hollow gd2o3:ln phosphors exhibit light emission under ultraviolet excitation, which may find promising applications in the fields of field emission displays (fed) and mri contrast agents. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000283315900067 |
| 公开日期 | 2012-04-25 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43342]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu YC,Yang PP,Wang WX,et al. Fabrication and photoluminescence properties of hollow Gd2O3:Ln (Ln = Eu3+, Sm3+) spheres via a sacrificial template method[J]. crystengcomm,2010,12(11):3717-3723. |
| APA | Liu YC,Yang PP,Wang WX,Dong HX,&Lin J.(2010).Fabrication and photoluminescence properties of hollow Gd2O3:Ln (Ln = Eu3+, Sm3+) spheres via a sacrificial template method.crystengcomm,12(11),3717-3723. |
| MLA | Liu YC,et al."Fabrication and photoluminescence properties of hollow Gd2O3:Ln (Ln = Eu3+, Sm3+) spheres via a sacrificial template method".crystengcomm 12.11(2010):3717-3723. |
入库方式： OAI收割
来源：长春应用化学研究所
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