Synthesis of Novel Star Polymers with Vinyl-Functionalized Hyperbranched Core via "Arm-First" Strategy
文献类型：期刊论文
| 作者 | Dong ZM ; Liu XH ; Liu HW ; Li YS |
| 刊名 | macromolecules
 |
| 出版日期 | 2010 |
| 卷号 | 43期号:19页码:7985-7992 |
| 关键词 | FREE-RADICAL POLYMERIZATION FRAGMENTATION TRANSFER POLYMERIZATION TRANSFER RAFT POLYMERIZATION SHAPED POLYSTYRENES DIVINYL MONOMER POLYDISPERSITY MACROMONOMERS ARCHITECTURES COPOLYMERS MICROGELS |
| ISSN号 | 0024-9297 |
| 通讯作者 | li ys |
| 中文摘要 | star polymers bearing vinyl-functionalized hyperbranched cores were successfully prepared at moderate-to-high monomer conversions (ca. 80%) via a modified "arm-first" strategy. this was achieved by reversible addition -fragmentation chain transfer polymerization of a methacrylate type asymmetrical divinyl monomer with thiobenzoate-capped polystyrenes as macro-chain-transfer agents (macro-ctas). neither intermolecular nor intramolecular cross-linking occurred up to high levels of monomer conversion. the molecular weights (mws) of macro-ctas significantly influence the structures of the resultant star polymers. a lower-mw macro-cta favors the formation of a star copolymer bearing big core and multiple short arms, whereas a higher-mw one is confined to the architecture bearing small core with only a few long arms. moreover, the ca. 70% pendant vinyl groups remained in the hyperbranched core can be directly modified using reactions such as epoxidation and uv initiated thiol-ene addition reactions, resulting in star polymers with various functional groups in the core. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000282478500019 |
| 公开日期 | 2012-04-25 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43378]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Dong ZM,Liu XH,Liu HW,et al. Synthesis of Novel Star Polymers with Vinyl-Functionalized Hyperbranched Core via "Arm-First" Strategy[J]. macromolecules,2010,43(19):7985-7992. |
| APA | Dong ZM,Liu XH,Liu HW,&Li YS.(2010).Synthesis of Novel Star Polymers with Vinyl-Functionalized Hyperbranched Core via "Arm-First" Strategy.macromolecules,43(19),7985-7992. |
| MLA | Dong ZM,et al."Synthesis of Novel Star Polymers with Vinyl-Functionalized Hyperbranched Core via "Arm-First" Strategy".macromolecules 43.19(2010):7985-7992. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。