Study on tonghaosu and its analogs: Isolation, structure identification and synthesis of antifeedant B-ring-homo-tonghaosu
文献类型：期刊论文
| 作者 | Li, C; Yin, BL; Xu, HH; Chiu, MH ; Wu, YL
|
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2004 |
| 卷号 | 22期号:1页码:92-99 |
| 关键词 | spiroketal B-ring-homo-tonghaosu dendranthema indicum var. aromaticum pieris brassicae antifeedant |
| 英文摘要 | The methanolic extract from a Chinese endemic Chrysanthemum plant, Dendranthema indicum var. aromaticum, was found to show high antifeeding activity against Pieris brassicae L., and by bioassay-guided separation, the active component, B-ring-homo-tonghaosu, 2-(2',4'-hexadiynylidene)-1,6-dioxaspiro-[4,5]-dec-3-ene (2) was isolated. Its structure was elucidated by comparing its spectroscopic data with those of 2 reported in the literatures. Furthermore new convenient total synthesis methods of B-ring-homo-tonghaosu were also developed to confirm its structure and make its further application in crop protection available. In addition, extensive comparison of spectroscopic data showed that the structure of compound 21 reported in literature should be revised to 2. |
| 学科主题 | Chemistry, Multidisciplinary |
| 类目[WOS] | Chemistry, Multidisciplinary |
| 研究领域[WOS] | Chemistry |
| 关键词[WOS] | ACETYLENES ; ANTHEMIDEAE ; COMPOSITAE |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000187998900019 |
| 公开日期 | 2012-04-05 |
| 源URL | [http://ir.kib.ac.cn:8080/handle/151853/5052]  |
| 专题 | 昆明植物研究所_植物化学与西部植物资源持续利用国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Bioorgan & Nat Prod Chem, Shanghai 200032, Peoples R China 2.Chinese Acad Sci, Kunming Inst Bot, State Key Lab Phytochem & Plant Resources W China, Kunming 650204, Yunnan, Peoples R China 3.S China Agr Univ, Lab Insect Toxicol, Guangzhou 510642, Guangdong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, C,Yin, BL,Xu, HH,et al. Study on tonghaosu and its analogs: Isolation, structure identification and synthesis of antifeedant B-ring-homo-tonghaosu[J]. CHINESE JOURNAL OF CHEMISTRY,2004,22(1):92-99. |
| APA | Li, C,Yin, BL,Xu, HH,Chiu, MH,&Wu, YL.(2004).Study on tonghaosu and its analogs: Isolation, structure identification and synthesis of antifeedant B-ring-homo-tonghaosu.CHINESE JOURNAL OF CHEMISTRY,22(1),92-99. |
| MLA | Li, C,et al."Study on tonghaosu and its analogs: Isolation, structure identification and synthesis of antifeedant B-ring-homo-tonghaosu".CHINESE JOURNAL OF CHEMISTRY 22.1(2004):92-99. |
入库方式： OAI收割
来源：昆明植物研究所
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