Preirradiation-Induced Emulsion Graft Polymerization of Glycidyl Methacrylate onto Poly(vinylidene fluoride) Powder
文献类型:期刊论文
作者 | Li, JY![]() |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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出版日期 | 2010 |
卷号 | 117期号:6页码:7 |
关键词 | fluoropolymers functionalization of polymers graft copolymers irradiation |
ISSN号 | 0021-8995 |
通讯作者 | Li, JY (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, 2019 Jialuo Rd, Shanghai 201800, Peoples R China |
英文摘要 | An epoxy-group-containing monomer, glycidyl methacrylate (GMA), was grafted onto poly(vinylidene fluoride) powder via preirradiation-induced emulsion graft polymerization. The existence of graft chains was proven by chemical structure characterization with Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy analysis. The degree of grafting was calculated by means of fluorine content analysis. A kinetic study indicated that, with the emulsion graft polymerization system, the GMA conversion rate was high, exceeding 80%. The variation in the molecular weight of the grafted polymer was measured by gel permeation chromatography, and its crystallinity was investigated with differential scanning calorimetry. The epoxy groups in graft chains were found to be suitable for further chemical modification. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 117: 3575-3581, 2010 |
学科主题 | Polymer Science |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000279958200060 |
公开日期 | 2012-04-11 |
源URL | [http://ir.sinap.ac.cn/handle/331007/7013] ![]() |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2004-2010年 |
推荐引用方式 GB/T 7714 | Li, JY. Preirradiation-Induced Emulsion Graft Polymerization of Glycidyl Methacrylate onto Poly(vinylidene fluoride) Powder[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2010,117(6):7. |
APA | Li, JY.(2010).Preirradiation-Induced Emulsion Graft Polymerization of Glycidyl Methacrylate onto Poly(vinylidene fluoride) Powder.JOURNAL OF APPLIED POLYMER SCIENCE,117(6),7. |
MLA | Li, JY."Preirradiation-Induced Emulsion Graft Polymerization of Glycidyl Methacrylate onto Poly(vinylidene fluoride) Powder".JOURNAL OF APPLIED POLYMER SCIENCE 117.6(2010):7. |
入库方式: OAI收割
来源:上海应用物理研究所
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