中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Role of primary reaction initiated by 254 nm UV light in the degradation of p-nitrophenol attacked by hydroxyl radicals

文献类型:期刊论文

作者Zhao, SF ; Ma, HJ ; Wang, M ; Cao, CQ ; Xiong, J ; Xu, YS ; Yao, SD
刊名PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
出版日期2010
卷号9期号:5页码:6
ISSN号1474-905X
通讯作者Yao, SD (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, POB 800-204, Shanghai 201800, Peoples R China
英文摘要The degradation kinetics of p-nitrophenol (p-NP) exposed to 254/185 nm UV light were studied in two modes, i.e., 254 nm UV light intensity enhanced mode and normal mode. It was observed that the extra 254 nm UV light source accelerated the degradation process both in the presence and the absence of oxygen. Considering that hydroxyl radical ((center dot)OH) is the dominant factor that causes the degradation of p-NP, the enhanced degradation that occurred in the presence of the extra light source was attributed to the synergistic effect between. OH attack and the primary reactions initiated by 254 nm UV light. The synergistic effect has been confirmed by 266 nm laser. ash photolysis (LFP) experiments. It is demonstrated that the phenoxy radical generated from the photoionization of p-NP is capable of reacting with. OH. On the basis of these results, it should be noted that UV light could cause more severe damage to p-NP attacked by. OH in aqueous solution.
学科主题Biochemistry & Molecular Biology; Biophysics; Chemistry
收录类别SCI
语种英语
WOS记录号WOS:000277318300012
公开日期2012-04-11
源URL[http://ir.sinap.ac.cn/handle/331007/7037]  
专题上海应用物理研究所_中科院上海应用物理研究所2004-2010年
推荐引用方式
GB/T 7714
Zhao, SF,Ma, HJ,Wang, M,et al. Role of primary reaction initiated by 254 nm UV light in the degradation of p-nitrophenol attacked by hydroxyl radicals[J]. PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES,2010,9(5):6.
APA Zhao, SF.,Ma, HJ.,Wang, M.,Cao, CQ.,Xiong, J.,...&Yao, SD.(2010).Role of primary reaction initiated by 254 nm UV light in the degradation of p-nitrophenol attacked by hydroxyl radicals.PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES,9(5),6.
MLA Zhao, SF,et al."Role of primary reaction initiated by 254 nm UV light in the degradation of p-nitrophenol attacked by hydroxyl radicals".PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES 9.5(2010):6.

入库方式: OAI收割

来源:上海应用物理研究所

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