Laser photolysis study on photochemical reactions in mixed solutions of [bmim] [PF6] and acetonitrile
文献类型：期刊论文
| 作者 | Xu, JJ（徐静静） ; Wu, GZ（吴国忠） ; Long, DW（龙德武） ; Yao, SD（姚思德） |
| 刊名 | SPECTROSCOPY AND SPECTRAL ANALYSIS
 |
| 出版日期 | 2007 |
| 卷号 | 27期号:10页码:1936 |
| ISSN号 | 1000-0593 |
| 通讯作者 | Xu, JJ (reprint author), Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China |
| 英文摘要 | Laser flash photolysis study was carried out for the first time in the binary mixture of room-temperature ionic liquid (RTIL) and traditional organic solvent. Photochemical properties of the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate [bmim][PF6] and its binary mixed solutions with MeCN were investigated by laser photolysis technique at an excitation wavelength of 355 nm, using anthraquinone (AQ) as a probe molecule. It was indicated that [bmim] [PF6] itself participates in the reaction with (3)AQ*. Moreover, along with the change in the ratio of RTIL to organic solvent, the decay reaction rate constant of (3)AQ* changes regularly and a critical point was observed at x(RTIL) =0.06. Before the critical point, the decay rate constant increases rapidly with increasing x(RTIL); however, it decreases obviously with increasing x(RTIL) after the critical point. The kinetic data are given, and the possible reaction mechanisms in mixed solutions are also speculated. |
| 学科主题 | Physics |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000250794700008 |
| 公开日期 | 2012-04-18 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/7765]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2004-2010年 |
| 推荐引用方式 GB/T 7714 | Xu, JJ,Wu, GZ,Long, DW,et al. Laser photolysis study on photochemical reactions in mixed solutions of [bmim] [PF6] and acetonitrile[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS,2007,27(10):1936. |
| APA | Xu, JJ,Wu, GZ,Long, DW,&Yao, SD.(2007).Laser photolysis study on photochemical reactions in mixed solutions of [bmim] [PF6] and acetonitrile.SPECTROSCOPY AND SPECTRAL ANALYSIS,27(10),1936. |
| MLA | Xu, JJ,et al."Laser photolysis study on photochemical reactions in mixed solutions of [bmim] [PF6] and acetonitrile".SPECTROSCOPY AND SPECTRAL ANALYSIS 27.10(2007):1936. |
入库方式： OAI收割
来源：上海应用物理研究所
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