Ethylene/hexene living copolymerization and ethylene/methyl 10-undecenoate copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands
文献类型:期刊论文
作者 | He LP ; Hong M ; Li BX ; Liu JY ; Li YS |
刊名 | polymer
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出版日期 | 2010 |
卷号 | 51期号:19页码:4336-4339 |
关键词 | OLEFIN POLYMERIZATION CATALYSTS IMINE CHELATE LIGANDS BLOCK-COPOLYMERS PROPYLENE BEHAVIOR |
ISSN号 | 0032-3861 |
通讯作者 | liu jy |
中文摘要 | several non-metallocene-type titanium(iv) complexes containing phenoxy-phosphine or thiophenoxy-phosphine ligands of type, (2-r-1-4-r-2-6-pph2-c6h2x)(2)ticl2 (2a: x o, r-1 = r-2 = t-bu; 2b x = o, r-1 = r-2 = cumyl, 2c x = s, r-1 = sime3, r-2 - h) have been synthesized by treating ticl4 with the corresponding ligands 2-r-1-4-r-2-6-pph2-c6h2xh in the presence of n-buli the complexes 2a-c were investigated as the catalysts for ethylene with 1-hexene and/or polar alkenes copolymerizations the catalytic activity and the comonomer incorporation were highly dependent upon catalyst and reaction conditions employed among these complexes, 2a can not only promote ethylene/1-hexene living copolymerization at room temperature, but also can utilize ethylene with methyl 10-undecenoate copolymerization (c) 2010 elsevier ltd all rights reserved |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000281506100007 |
公开日期 | 2012-04-26 |
源URL | [http://ir.ciac.jl.cn/handle/322003/43489] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | He LP,Hong M,Li BX,et al. Ethylene/hexene living copolymerization and ethylene/methyl 10-undecenoate copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands[J]. polymer,2010,51(19):4336-4339. |
APA | He LP,Hong M,Li BX,Liu JY,&Li YS.(2010).Ethylene/hexene living copolymerization and ethylene/methyl 10-undecenoate copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands.polymer,51(19),4336-4339. |
MLA | He LP,et al."Ethylene/hexene living copolymerization and ethylene/methyl 10-undecenoate copolymerization by titanium complexes bearing phenoxy-phosphine or thiophenoxy-phosphine ligands".polymer 51.19(2010):4336-4339. |
入库方式: OAI收割
来源:长春应用化学研究所
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