Broad absorbing low-bandgap polythiophene derivatives incorporating separate and content-tunable benzothiadiazole and carbazole moieties for polymer solar cells
文献类型：期刊论文
| 作者 | Shi F ; Fang G ; Liang FS ; Wang LF ; Mu ZC ; Zhang XT ; Xie ZY ; Su ZM |
| 刊名 | european polymer journal
 |
| 出版日期 | 2010 |
| 卷号 | 46期号:8页码:1770-1777 |
| 关键词 | THIN-FILM TRANSISTORS POLY(2 PHOTOVOLTAIC CELLS 7-CARBAZOLE) THIOPHENE COPOLYMERS CONJUGATED POLYMERS ABSORPTION-SPECTRA PERFORMANCE EFFICIENCY MOBILITY HETEROJUNCTIONS |
| ISSN号 | 0014-3057 |
| 通讯作者 | liang fs |
| 中文摘要 | three novel low-bandgap (lgb) conjugated polythiophenes (pthbtd(m)cz(n)) incorporating separate and content-tunable benzothiadiazole and carbazole moieties have been designed and synthesized for application in bulk heterojunction polymer solar cells (pscs). the absorption spectral, thermal, electrochemical and photovoltaic properties of the random copolymers were investigated. broad absorption from a single polymer covering the visible region from 300 to 800 nm was observed, which was ideal for highly efficient harvesting of the solar spectrum. dsc analysis showed that the polymers readily crystallized, indicating highly ordered intermolecular packing, which is beneficial for efficient charge-carrier transport. electrochemical studies indicate desirable homo/lumo levels that enable a high open-circuit voltage while blending them with fullerene derivatives as electron acceptors. polymer solar cells using 1:1 or 1:2 wt/wt polymer: pc61bm (methanofullerene [6,6-phenyl c61-butyric acid methyl ester] blends as the photoactive layers were fabricated and characterized. the preliminary investigation on the photovoltaic device of the pthbtd(m)cz(n) polymers gave similar power conversion efficiency of 1.1-1.2% with v-oc, of 0.64-0.68 v under simulated solar light am 1.5 g (100 mw/cm(2)). (c) 2010 elsevier ltd. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000280941400013 |
| 公开日期 | 2012-04-26 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43518]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Shi F,Fang G,Liang FS,et al. Broad absorbing low-bandgap polythiophene derivatives incorporating separate and content-tunable benzothiadiazole and carbazole moieties for polymer solar cells[J]. european polymer journal,2010,46(8):1770-1777. |
| APA | Shi F.,Fang G.,Liang FS.,Wang LF.,Mu ZC.,...&Su ZM.(2010).Broad absorbing low-bandgap polythiophene derivatives incorporating separate and content-tunable benzothiadiazole and carbazole moieties for polymer solar cells.european polymer journal,46(8),1770-1777. |
| MLA | Shi F,et al."Broad absorbing low-bandgap polythiophene derivatives incorporating separate and content-tunable benzothiadiazole and carbazole moieties for polymer solar cells".european polymer journal 46.8(2010):1770-1777. |
入库方式： OAI收割
来源：长春应用化学研究所
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