Cylinder-to-rod-to-sphere evolution of complex micelles in solution and their corresponding solvent-induced crystallization process
文献类型:期刊论文
作者 | Huang WH ; Luo CX ; Wang HF ; Han YC |
刊名 | polymer international
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出版日期 | 2010 |
卷号 | 59期号:8页码:1064-1070 |
关键词 | CORE-SHELL NANOPARTICLES ACID) DIBLOCK COPOLYMERS BLOCK-COPOLYMERS DILUTE-SOLUTION THIN-FILMS POLYMER CRYSTALLIZATION SELF-ORGANIZATION CONFINED CRYSTALLIZATION CRYSTAL-GROWTH MORPHOLOGY |
ISSN号 | 0959-8103 |
通讯作者 | han yc |
中文摘要 | in a previous paper, we investigated the solvent-induced crystallization of films made up of spherical micelles, which were prepared by mixing polystyrene-block-poly(acrylic acid) and polystyrene-block-poly(2-vinylpyridine)-block-poly(ethylene oxide) in the neutral solvent n,n-dimethylformamide (dmf). in the work reported in the present paper, we further studied the cylinder-to-rod-to-sphere evolution of complex micelles in solution and their corresponding solvent-induced crystallization process. the initial morphology of the micelles in the solution was cylindrical due to a rapid growth of micelles with high unimer concentration, and spheres became the dominant form after storage at room temperature for a longer time. regular square platelets can form after a certain period of treatment for all micelles in dmf vapor for sufficient time. however, the kinetics of their solvent-induced crystallization process is quite different. the aggregation and subsequent nucleation of poly(ethylene oxide) blocks are determined by the distribution of crystallizable poly(ethylene oxide) blocks in the films. (c) 2010 society of chemical industry |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000280677700006 |
公开日期 | 2012-04-26 |
源URL | [http://ir.ciac.jl.cn/handle/322003/43547] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Huang WH,Luo CX,Wang HF,et al. Cylinder-to-rod-to-sphere evolution of complex micelles in solution and their corresponding solvent-induced crystallization process[J]. polymer international,2010,59(8):1064-1070. |
APA | Huang WH,Luo CX,Wang HF,&Han YC.(2010).Cylinder-to-rod-to-sphere evolution of complex micelles in solution and their corresponding solvent-induced crystallization process.polymer international,59(8),1064-1070. |
MLA | Huang WH,et al."Cylinder-to-rod-to-sphere evolution of complex micelles in solution and their corresponding solvent-induced crystallization process".polymer international 59.8(2010):1064-1070. |
入库方式: OAI收割
来源:长春应用化学研究所
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