中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Cylinder-to-rod-to-sphere evolution of complex micelles in solution and their corresponding solvent-induced crystallization process

文献类型:期刊论文

作者Huang WH ; Luo CX ; Wang HF ; Han YC
刊名polymer international
出版日期2010
卷号59期号:8页码:1064-1070
关键词CORE-SHELL NANOPARTICLES ACID) DIBLOCK COPOLYMERS BLOCK-COPOLYMERS DILUTE-SOLUTION THIN-FILMS POLYMER CRYSTALLIZATION SELF-ORGANIZATION CONFINED CRYSTALLIZATION CRYSTAL-GROWTH MORPHOLOGY
ISSN号0959-8103
通讯作者han yc
中文摘要in a previous paper, we investigated the solvent-induced crystallization of films made up of spherical micelles, which were prepared by mixing polystyrene-block-poly(acrylic acid) and polystyrene-block-poly(2-vinylpyridine)-block-poly(ethylene oxide) in the neutral solvent n,n-dimethylformamide (dmf). in the work reported in the present paper, we further studied the cylinder-to-rod-to-sphere evolution of complex micelles in solution and their corresponding solvent-induced crystallization process. the initial morphology of the micelles in the solution was cylindrical due to a rapid growth of micelles with high unimer concentration, and spheres became the dominant form after storage at room temperature for a longer time. regular square platelets can form after a certain period of treatment for all micelles in dmf vapor for sufficient time. however, the kinetics of their solvent-induced crystallization process is quite different. the aggregation and subsequent nucleation of poly(ethylene oxide) blocks are determined by the distribution of crystallizable poly(ethylene oxide) blocks in the films. (c) 2010 society of chemical industry
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000280677700006
公开日期2012-04-26
源URL[http://ir.ciac.jl.cn/handle/322003/43547]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Huang WH,Luo CX,Wang HF,et al. Cylinder-to-rod-to-sphere evolution of complex micelles in solution and their corresponding solvent-induced crystallization process[J]. polymer international,2010,59(8):1064-1070.
APA Huang WH,Luo CX,Wang HF,&Han YC.(2010).Cylinder-to-rod-to-sphere evolution of complex micelles in solution and their corresponding solvent-induced crystallization process.polymer international,59(8),1064-1070.
MLA Huang WH,et al."Cylinder-to-rod-to-sphere evolution of complex micelles in solution and their corresponding solvent-induced crystallization process".polymer international 59.8(2010):1064-1070.

入库方式: OAI收割

来源:长春应用化学研究所

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