Polyfluorene-Based Push-Pull Type Functional Materials for Write-Once-Read-Many-Times Memory Devices
文献类型:期刊论文
作者 | Zhuang XD ; Chen Y ; Li BX ; Ma DG ; Zhang B ; Li YX |
刊名 | chemistry of materials
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出版日期 | 2010 |
卷号 | 22期号:15页码:4455-4461 |
关键词 | PHOTOINDUCED ELECTRON-TRANSFER STRUCTURE-PROPERTY RELATIONSHIPS CHARGE-TRANSFER COMPLEX LIGHT-EMITTING-DIODES ELECTROCHEMICAL PROPERTIES SOLAR-CELLS THIN-FILMS CONJUGATED COPOLYMERS PHOTOVOLTAIC DEVICES PENDANT GROUPS |
ISSN号 | 0897-4756 |
通讯作者 | chen y |
中文摘要 | a highly soluble polyfluorene-based copolymer containing electron-rich triphenylamine (tpa) and electron-poor 9,9-bis(3,4-bis(3,4-dicyanophenoxy)phenyl side chains in the c-9 position of the fluorene unit was synthesized under yamamoto conditions. by applying 306 nm as excitation wavelength, the resultant polymer exhibits strong photoluminescence with maximum emission peaks centered at 413 and 433(sh) nm in chloroform. the calculated highest occupied molecular orbital (homo), lowest unoccupied molecular orbital (lumo), energy bandgap, ionization potential, and electron affinity are -5.66, -3.44, 2.22, 5.92, and 3.70 ev, respectively. the as-fabricated polymer film exhibited typical stable write-once-read-many-times (worm) memory characteristics, which are desirable for ultralow-cost permanent storage of digital images. the currents in both on and off states did not show any degradation, suggesting good device stability. the on/off current ratio observed in the sweep i-vcharacteristics at +1.0 v is 6.1 x 10(3). the conduction mechanism through ito/polymer/al device is discussed. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000280609800017 |
公开日期 | 2012-04-26 |
源URL | [http://ir.ciac.jl.cn/handle/322003/43557] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhuang XD,Chen Y,Li BX,et al. Polyfluorene-Based Push-Pull Type Functional Materials for Write-Once-Read-Many-Times Memory Devices[J]. chemistry of materials,2010,22(15):4455-4461. |
APA | Zhuang XD,Chen Y,Li BX,Ma DG,Zhang B,&Li YX.(2010).Polyfluorene-Based Push-Pull Type Functional Materials for Write-Once-Read-Many-Times Memory Devices.chemistry of materials,22(15),4455-4461. |
MLA | Zhuang XD,et al."Polyfluorene-Based Push-Pull Type Functional Materials for Write-Once-Read-Many-Times Memory Devices".chemistry of materials 22.15(2010):4455-4461. |
入库方式: OAI收割
来源:长春应用化学研究所
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