Synthesis of novel poly(ethylene-ter-1-hexene-ter-dicyclopentadiene)s using bis (beta-enaminoketonato)titanium catalysts and their applications in preparing polyolefin-graft-poly(epsilon-polycaprolactone)
文献类型：期刊论文
| 作者 | Hong MA ; Pan L ; Li BX ; Li YS |
| 刊名 | polymer
 |
| 出版日期 | 2010 |
| 卷号 | 51期号:16页码:3636-3643 |
| 关键词 | TITANIUM COMPLEXES GRAFT-COPOLYMERS REGIOSELECTIVE COPOLYMERIZATION EFFICIENT FUNCTIONALIZATION ETHYLENE COPOLYMERIZATION METALLOCENE CATALYSIS POLYOLEFIN ELASTOMERS RADICAL INITIATOR CHELATE LIGANDS CYCLIC DIENES |
| ISSN号 | 0032-3861 |
| 通讯作者 | li ys |
| 中文摘要 | novel terpolymers containing ethylene, 1-hexene and dicyclopentadiene (dcpd) were synthesized using bis(beta-enaminoketonato)titanium catalysts [phn=c(r-2)chc(r-1)o](2)ticl2 (1a: r-1 = ph, r-2 = cf3; 1b: r-1 = cf3, r-2 = ch3). in the presence of modified methylaluminoxane, these catalysts afforded terpolymers with a broad range of monomer compositions and unimodal molecular weight distributions. c-13 nmr spectra reveal the exclusive insertion manner of dcpd maintained under various reaction conditions. dsc results show the melting temperature and the glass transition temperature are very sensitive to the terpolymer composition and the morphology can be easily tuned from semicrystalline state to amorphous state. with ethylene/1-hexene/dcpd molar ratio about 67/28/5, the terpolymer exhibits low glass transition temperature (t-g = -50 degrees c) and has a great potential to serve as polyolefin elastomer. additionally, the terpolymer containing 4.3 mol% 1-hexene and 1.6 mol% dcpd was served as the "reactive intermediate polyolefin" for pcl graft reaction. the composition of graft copolymer was well controllable and high graft efficiency was observed. the microscopy studies in conjunction with the tensile tests revealed that pcl graft copolymer is the effective compatibilizer for polyethylene/polar polymer blends by improving the interfacial adhesion between separated phases. (c) 2010 elsevier ltd. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000280263200006 |
| 公开日期 | 2012-04-26 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43582]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Hong MA,Pan L,Li BX,et al. Synthesis of novel poly(ethylene-ter-1-hexene-ter-dicyclopentadiene)s using bis (beta-enaminoketonato)titanium catalysts and their applications in preparing polyolefin-graft-poly(epsilon-polycaprolactone)[J]. polymer,2010,51(16):3636-3643. |
| APA | Hong MA,Pan L,Li BX,&Li YS.(2010).Synthesis of novel poly(ethylene-ter-1-hexene-ter-dicyclopentadiene)s using bis (beta-enaminoketonato)titanium catalysts and their applications in preparing polyolefin-graft-poly(epsilon-polycaprolactone).polymer,51(16),3636-3643. |
| MLA | Hong MA,et al."Synthesis of novel poly(ethylene-ter-1-hexene-ter-dicyclopentadiene)s using bis (beta-enaminoketonato)titanium catalysts and their applications in preparing polyolefin-graft-poly(epsilon-polycaprolactone)".polymer 51.16(2010):3636-3643. |
入库方式： OAI收割
来源：长春应用化学研究所
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