中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization

文献类型:期刊论文

作者Zhang ZC ; Cui DM ; Trifonov AA
刊名european journal of inorganic chemistry
出版日期2010
期号18页码:2861-2866
关键词RING-OPENING POLYMERIZATION N C5ME5/ER-LIGATED SAMARIUM(II) COMPLEXES O MULTIDENTATE LIGANDS AMIDO-CYCLOPENTADIENYL LIGAND METHYL-METHACRYLATE BLOCK-COPOLYMERIZATION STRUCTURAL-CHARACTERIZATION ETHYLENE POLYMERIZATION STYRENE POLYMERIZATION LANTHANIDE COMPLEXES
ISSN号1434-1948
通讯作者cui dm
中文摘要a series of rare-earth metal alkyl complexes supported by a heteroscorpionate ligand were prepared and structurally characterized. x-ray diffraction analysis revealed that the heteroscorpionate ligand is face-capping on the rare-earth metal in k(3) mode, making the configuration of the afforded chalky! metal complexes similar to that of half-metallocenes. these complexes are capable of polymerizing methyl methacrylate, with the lutetium complex displaying the highest activity even at low temperature. the poly(methyl methacrylate) obtained is syndiotactically enriched with narrow molecular weight distribution.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000279975400035
公开日期2012-04-26
源URL[http://ir.ciac.jl.cn/handle/322003/43603]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Zhang ZC,Cui DM,Trifonov AA. Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization[J]. european journal of inorganic chemistry,2010(18):2861-2866.
APA Zhang ZC,Cui DM,&Trifonov AA.(2010).Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization.european journal of inorganic chemistry(18),2861-2866.
MLA Zhang ZC,et al."Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization".european journal of inorganic chemistry .18(2010):2861-2866.

入库方式: OAI收割

来源:长春应用化学研究所

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