Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization
文献类型：期刊论文
| 作者 | Zhang ZC ; Cui DM ; Trifonov AA |
| 刊名 | european journal of inorganic chemistry
 |
| 出版日期 | 2010 |
| 期号 | 18页码:2861-2866 |
| 关键词 | RING-OPENING POLYMERIZATION N C5ME5/ER-LIGATED SAMARIUM(II) COMPLEXES O MULTIDENTATE LIGANDS AMIDO-CYCLOPENTADIENYL LIGAND METHYL-METHACRYLATE BLOCK-COPOLYMERIZATION STRUCTURAL-CHARACTERIZATION ETHYLENE POLYMERIZATION STYRENE POLYMERIZATION LANTHANIDE COMPLEXES |
| ISSN号 | 1434-1948 |
| 通讯作者 | cui dm |
| 中文摘要 | a series of rare-earth metal alkyl complexes supported by a heteroscorpionate ligand were prepared and structurally characterized. x-ray diffraction analysis revealed that the heteroscorpionate ligand is face-capping on the rare-earth metal in k(3) mode, making the configuration of the afforded chalky! metal complexes similar to that of half-metallocenes. these complexes are capable of polymerizing methyl methacrylate, with the lutetium complex displaying the highest activity even at low temperature. the poly(methyl methacrylate) obtained is syndiotactically enriched with narrow molecular weight distribution. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000279975400035 |
| 公开日期 | 2012-04-26 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43603]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhang ZC,Cui DM,Trifonov AA. Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization[J]. european journal of inorganic chemistry,2010(18):2861-2866. |
| APA | Zhang ZC,Cui DM,&Trifonov AA.(2010).Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization.european journal of inorganic chemistry(18),2861-2866. |
| MLA | Zhang ZC,et al."Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization".european journal of inorganic chemistry .18(2010):2861-2866. |
入库方式： OAI收割
来源：长春应用化学研究所
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