Synthesis of hyperbranched polymers via a facile self-condensing vinyl polymerization system - Glycidyl methacrylate/Cp2TiCl2/Zn
文献类型：期刊论文
| 作者 | Liu XH ; Bao YM ; Tang XL ; Li YS |
| 刊名 | polymer
 |
| 出版日期 | 2010 |
| 卷号 | 51期号:13页码:2857-2863 |
| 关键词 | RING-OPENING POLYMERIZATION ONE-POT SYNTHESIS RADICAL STYRENE POLYMERIZATIONS BLOCK-COPOLYMERS EPSILON-CAPROLACTONE BRANCHED POLY(N-ISOPROPYLACRYLAMIDE) ANIONIC-POLYMERIZATION ALIPHATIC POLYESTERS CLICK CHEMISTRY STAR POLYMERS |
| ISSN号 | 0032-3861 |
| 通讯作者 | li ys |
| 中文摘要 | a facile self-condensing vinyl polymerization (scvp) system, the combination of glycidyl methacrylate, cp2ticl2 and zn, has been firstly used to prepare novel hyperbranched polymers, consisting of vinyl polymers as the backbone, and cyclic ester polymers (poly(c-caprolactone) or poly(l-lactide)) as the side chains. the polymerizations are initiated by the epoxide radical ring-opening catalyzed by cp2ti(iii)cl which is generated in situ via the reaction of cp2ticl2 with zn. the key to success is that the polymerizations can proceed concurrently via two dissimilar chemistries possessing the opposite active initiating species, including ring-opening polymerization (rop) and controlled/living radical polymerization (crp). we have demonstrated that this facile one-step polymerization technique can be applied successfully to prepare highly branched polymers with a multiplicity of end reactive functionalities including ti alkoxide, hydroxyl and vinyl functional groups. (c) 2010 elsevier ltd. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000279158800008 |
| 公开日期 | 2012-04-26 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43634]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu XH,Bao YM,Tang XL,et al. Synthesis of hyperbranched polymers via a facile self-condensing vinyl polymerization system - Glycidyl methacrylate/Cp2TiCl2/Zn[J]. polymer,2010,51(13):2857-2863. |
| APA | Liu XH,Bao YM,Tang XL,&Li YS.(2010).Synthesis of hyperbranched polymers via a facile self-condensing vinyl polymerization system - Glycidyl methacrylate/Cp2TiCl2/Zn.polymer,51(13),2857-2863. |
| MLA | Liu XH,et al."Synthesis of hyperbranched polymers via a facile self-condensing vinyl polymerization system - Glycidyl methacrylate/Cp2TiCl2/Zn".polymer 51.13(2010):2857-2863. |
入库方式： OAI收割
来源：长春应用化学研究所
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