[Zn(HPO3)(C11N2O2H12)] and [Zn-3(H2O)(PO4)(HPO4)(C6H9N3O2)(2) (C6H8N3O2)]: homochiral zinc phosphite/phosphate networks with biofunctional amino acids
文献类型：期刊论文
| 作者 | Dong ZJ ; Zhao L ; Liang ZQ ; Chen P ; Yan Y ; Li JY ; Yu JH ; Xu RR |
| 刊名 | dalton transactions
 |
| 出版日期 | 2010 |
| 卷号 | 39期号:23页码:5439-5445 |
| 关键词 | CHIRAL METAL-COMPLEX HYDROTHERMAL SYNTHESIS HELICAL CHANNELS MOLECULAR RECOGNITION SOLID-STATE L-HISTIDINE BUILT-UP PHOSPHATE FRAMEWORK ALUMINOPHOSPHATE |
| ISSN号 | 1477-9226 |
| 通讯作者 | li jy |
| 中文摘要 | two new homochiral inorganic-organic hybrid frameworks [zn(hpo3)(c11n2o2h12)] (denoted as znhpo-cj56) and [zn-3(h2o)(po4)(hpo4)(c6h9n3o2)(2)(c6h8n3o2)] (denoted as znpo-cj57) have been hydrothermally synthesized in the presence of chiral amino acids l-trypophan and l-histidine. both of their inorganic networks are featured by one-dimensional (1d) edge-sharing zn2p2 ladder-like chains. the amino acid molecules as the ligands are grafted onto two sides of the chain. extensive n-h...o and o-h...o hydrogen bonds of host guest are formed to stable the chiral structures of znhpo-cj56 and znpo-cj57. it is noteworthy that the original chirality of the amino acid molecules is maintained in the structures of the as-synthesized compounds, and the resulting crystals have an enantiometric excess, which is confirmed by the solid state vibrational circular dichroism (vcd). their syntheses, structures, and luminescence properties have been studied in detail. the formation of such chiral one-dimensional structures with multi-amino acids might be potentially applied in chiral catalysis, biochemistry processes or as functional materials. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000278965700006 |
| 公开日期 | 2012-04-26 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/43655]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Dong ZJ,Zhao L,Liang ZQ,et al. [Zn(HPO3)(C11N2O2H12)] and [Zn-3(H2O)(PO4)(HPO4)(C6H9N3O2)(2) (C6H8N3O2)]: homochiral zinc phosphite/phosphate networks with biofunctional amino acids[J]. dalton transactions,2010,39(23):5439-5445. |
| APA | Dong ZJ.,Zhao L.,Liang ZQ.,Chen P.,Yan Y.,...&Xu RR.(2010).[Zn(HPO3)(C11N2O2H12)] and [Zn-3(H2O)(PO4)(HPO4)(C6H9N3O2)(2) (C6H8N3O2)]: homochiral zinc phosphite/phosphate networks with biofunctional amino acids.dalton transactions,39(23),5439-5445. |
| MLA | Dong ZJ,et al."[Zn(HPO3)(C11N2O2H12)] and [Zn-3(H2O)(PO4)(HPO4)(C6H9N3O2)(2) (C6H8N3O2)]: homochiral zinc phosphite/phosphate networks with biofunctional amino acids".dalton transactions 39.23(2010):5439-5445. |
入库方式： OAI收割
来源：长春应用化学研究所
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