Theoretical Investigations of the Local Structure Distortion and EPR Parameter for Ni(2+)-doped Perovskite Fluorides
文献类型：期刊论文
| 作者 | X. M. Cao ; X. Y. Kuang ; C. G. Li ; R. P. Chai |
| 刊名 | Chinese Journal of Chemical Physics
 |
| 出版日期 | 2011 |
| 卷号 | 24期号:2页码:167-172 |
| 关键词 | Complete energy matrix Double spin-orbit coupling parameter model Local structure distortion electron-paramagnetic-resonance atomic screening constants scf functions ligand-field ni-2+ ions kznf3 rbcdf3 ni2 crystals clusters |
| ISSN号 | 1674-0068 |
| 中文摘要 | By analyzing the optical spectra and electron paramagnetic resonance parameter D, the local structure distortion of (NiF(6))(4-) clusters in AMF(3) (A=K, Rb; M=Zn, Cd, Ca) and K(2)ZnF(4) series are studied using the complete energy matrix based on the double spin-orbit coupling parameter model for configuration ions in a tetragonal ligand field. The results indicate that the contribution of ligand to spin-orbit coupling interaction should be considered for our studied systems. Moreover, the relationships between D and the spin-obit coupling coefficients as well as the average parameter and the divergent parameter are discussed. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/30244]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | X. M. Cao,X. Y. Kuang,C. G. Li,et al. Theoretical Investigations of the Local Structure Distortion and EPR Parameter for Ni(2+)-doped Perovskite Fluorides[J]. Chinese Journal of Chemical Physics,2011,24(2):167-172. |
| APA | X. M. Cao,X. Y. Kuang,C. G. Li,&R. P. Chai.(2011).Theoretical Investigations of the Local Structure Distortion and EPR Parameter for Ni(2+)-doped Perovskite Fluorides.Chinese Journal of Chemical Physics,24(2),167-172. |
| MLA | X. M. Cao,et al."Theoretical Investigations of the Local Structure Distortion and EPR Parameter for Ni(2+)-doped Perovskite Fluorides".Chinese Journal of Chemical Physics 24.2(2011):167-172. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。