Influence of the beta coefficient in the superposition model on the spin-Hamiltonian parameters of the ground state of paramagnetic ions
文献类型:期刊论文
作者 | W. L. Feng ; X. Z. Yang ; Y. Jin ; T. X. Zeng ; R. F. Li |
刊名 | Physica Scripta
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出版日期 | 2011 |
卷号 | 83期号:6 |
关键词 | csmgcl3 crystals trigonal sites epr-spectra cr3+ ions field resonance symmetry centers |
ISSN号 | 0031-8949 |
中文摘要 | The relationship between the beta coefficient in the superposition model and the spin-Hamiltonian (SH) parameters of ground state of the paramagnetic ion is studied based on the crystal-field theory. The complete diagonalization method is used in calculations and is used in studies of the variation of the SH parameters of the ground state with the beta coefficient for the CsMgCl(3) : Ni(2+)(Pd(2+)) system. These studies show that beta has almost no effect on the theoretical values of g-factors (g(parallel to) and g(perpendicular to)) of the ground state, but has a strong effect on the zero-field splitting parameter D. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://210.72.142.130/handle/321006/30327] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. L. Feng,X. Z. Yang,Y. Jin,et al. Influence of the beta coefficient in the superposition model on the spin-Hamiltonian parameters of the ground state of paramagnetic ions[J]. Physica Scripta,2011,83(6). |
APA | W. L. Feng,X. Z. Yang,Y. Jin,T. X. Zeng,&R. F. Li.(2011).Influence of the beta coefficient in the superposition model on the spin-Hamiltonian parameters of the ground state of paramagnetic ions.Physica Scripta,83(6). |
MLA | W. L. Feng,et al."Influence of the beta coefficient in the superposition model on the spin-Hamiltonian parameters of the ground state of paramagnetic ions".Physica Scripta 83.6(2011). |
入库方式: OAI收割
来源:金属研究所
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