Corrosion protection of stainless steel by separate polypyrrole electrode in acid solutions
文献类型:期刊论文
作者 | J. Hu ; H. Zhu ; Y. Ma ; T. Yi ; X. Mao ; A. Lin ; F. Gan |
刊名 | Materials and Corrosion-Werkstoffe Und Korrosion
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出版日期 | 2011 |
卷号 | 62期号:1页码:68-73 |
关键词 | galvanic anodic protection organic metal polyaniline coated mild-steel conducting polymers doped polyaniline ferrous-metals carbon-steel coatings iron passivation |
ISSN号 | 0947-5117 |
中文摘要 | Galvanic anodic protection (GAP) of stainless steels by doped polypyrrole (PPy) was investigated using chemically synthesized PPy. Separate PPy powder-pressed electrodes with different surface areas were prepared. Electrochemical properties of PPy electrodes were studied by open circuit potentials (OCPs) and potentiostatic polarization. PPy powder-pressed electrodes were coupled with 410-stainless steel electrodes in different concentrations of sulfuric acid solutions, 5 M phosphoric acid solution, and industrial phosphoric acid solution (5 M phosphoric acid + 0.05% chloride ion). Remarkable shift of OCP to the positive direction and sharp decrease of corrosion rate were observed during the coupling experiments, which implies that 410-stainless steel was transferred to passive state. Results also showed that PPy electrode with sufficient surface area can provide corrosion protection to 410-stainless steel electrode in highly corrosive acid solution. Based on the experiment results, GAP provided by PPy and PANi (synthesized under similar conditions) was compared. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://210.72.142.130/handle/321006/30393] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | J. Hu,H. Zhu,Y. Ma,et al. Corrosion protection of stainless steel by separate polypyrrole electrode in acid solutions[J]. Materials and Corrosion-Werkstoffe Und Korrosion,2011,62(1):68-73. |
APA | J. Hu.,H. Zhu.,Y. Ma.,T. Yi.,X. Mao.,...&F. Gan.(2011).Corrosion protection of stainless steel by separate polypyrrole electrode in acid solutions.Materials and Corrosion-Werkstoffe Und Korrosion,62(1),68-73. |
MLA | J. Hu,et al."Corrosion protection of stainless steel by separate polypyrrole electrode in acid solutions".Materials and Corrosion-Werkstoffe Und Korrosion 62.1(2011):68-73. |
入库方式: OAI收割
来源:金属研究所
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