Investigation of the local structure and ZFS parameter for Ni(2+) (V(2+)) ions in Zinc Fluosilicate at different pressure
文献类型：期刊论文
| 作者 | C. G. Li ; X. Y. Kuang ; Y. R. Zhao ; R. P. Chai ; H. Li |
| 刊名 | Chemical Physics Letters
 |
| 出版日期 | 2011 |
| 卷号 | 512期号:4-6页码:263-268 |
| 关键词 | atomic screening constants scf functions epr-spectra temperature crystals nickel zno distortions dependence cluster |
| ISSN号 | 0009-2614 |
| 中文摘要 | Based on the complete energy matrix approach, the local structure and zero field splitting (ZFS) parameter for ZnSiF(6)center dot 6H(2)O:Ni(2+) (V(2+)) systems are theoretically studied for 3d(n) (n = 3, 8) ions in trigonal symmetry at different pressure. In this approach, the contributions from the admixture of d orbitals of the central ions with the p orbitals of the ligands are considered. In addition, the relationships between the ZFS parameter D and the pressure P as well as the local structure parameter theta are discussed. The effects of the average parameter zeta(1) and the different parameter zeta(2) on the ZFS parameter D are analyzed. Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/30449]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | C. G. Li,X. Y. Kuang,Y. R. Zhao,et al. Investigation of the local structure and ZFS parameter for Ni(2+) (V(2+)) ions in Zinc Fluosilicate at different pressure[J]. Chemical Physics Letters,2011,512(4-6):263-268. |
| APA | C. G. Li,X. Y. Kuang,Y. R. Zhao,R. P. Chai,&H. Li.(2011).Investigation of the local structure and ZFS parameter for Ni(2+) (V(2+)) ions in Zinc Fluosilicate at different pressure.Chemical Physics Letters,512(4-6),263-268. |
| MLA | C. G. Li,et al."Investigation of the local structure and ZFS parameter for Ni(2+) (V(2+)) ions in Zinc Fluosilicate at different pressure".Chemical Physics Letters 512.4-6(2011):263-268. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。