Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag(2+) crystals
文献类型：期刊论文
| 作者 | W. L. Li ; X. M. Li ; W. L. Feng ; W. J. Yang ; C. Y. Tao |
| 刊名 | Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy
 |
| 出版日期 | 2011 |
| 卷号 | 79期号:5页码:1308-1310 |
| 关键词 | Electron paramagnetic resonance Double spin-orbit coupling model NaCl Ag(2+) spin-hamiltonian parameters atomic screening constants paramagnetic-resonance single-crystals optical-spectra scf functions ions electrons sites v3+ |
| ISSN号 | 1386-1425 |
| 中文摘要 | In this paper, it is considered that the local structure of the (AgCl(6))(4-) cluster for the NaCI: Ag(2+) crystal is of the axially elongational D(4h) symmetry which possesses the weaker rhombic distortion at < 001 > lattice site. The mechanism for an admixture of the (2)A(1g) into the ground state (2)B(1g) is taken into account. The electron paramagnetic resonance (EPR)g factors of NaCl: Ag(2+) are studied by using the double spin-orbit coupling model and an approximation of a semiempirical molecular orbit. The EPR g factors for the NaCl: Ag(2+) crystals are reasonably explained as well as the good agreement between the calculated values and the experimental data is obtained. (C) 2011 Elsevier B.V. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/30485]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | W. L. Li,X. M. Li,W. L. Feng,et al. Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag(2+) crystals[J]. Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,2011,79(5):1308-1310. |
| APA | W. L. Li,X. M. Li,W. L. Feng,W. J. Yang,&C. Y. Tao.(2011).Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag(2+) crystals.Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy,79(5),1308-1310. |
| MLA | W. L. Li,et al."Theoretical investigation for the EPR g-factors of the mixed ground state in NaCl: Ag(2+) crystals".Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy 79.5(2011):1308-1310. |
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来源：金属研究所
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