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Production of iron and oxygen in molten K(2)CO(3)-Na(2)CO(3) by electrochemically splitting Fe(2)O(3) using a cost affordable inert anode

文献类型:期刊论文

作者H. Y. Yin ; D. Y. Tang ; H. Zhu ; Y. Zhang ; D. H. Wang
刊名Electrochemistry Communications
出版日期2011
卷号13期号:12页码:1521-1524
关键词Molten salt electrochemistry Iron Molten carbonate Inert anode Green process Oxygen production electrolytic formation sodium-hydroxide carbonates behavior oxide cell gas
ISSN号1388-2481
中文摘要Iron oxide was electrochemically split into iron and oxygen gas in molten Na(2)CO(3)-K(2)CO(3) at 750 degrees C using a solid iron oxide cathode and a Ni10Cu11Fe alloy inert anode. Fe(2)O(3) was electrochemically reduced to Fe on the cathode, releasing oxygen anions into the electrolyte and which were oxidized on the anode to generate O(2). The cathodic current efficiency was as high as 95% and the energy consumption for producing 1 kg iron was 2.87 kWh, only half of the current industrial energy consumption of blast-furnace steel production. Due to the cost-affordable inert anode and the high energy efficiency, the method demonstrated in this work shows promise as a practical "green" iron production process. (C) 2011 Elsevier B.V. All rights reserved.
原文出处://WOS:000298940800061
公开日期2012-04-13
源URL[http://210.72.142.130/handle/321006/30845]  
专题金属研究所_中国科学院金属研究所
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GB/T 7714
H. Y. Yin,D. Y. Tang,H. Zhu,et al. Production of iron and oxygen in molten K(2)CO(3)-Na(2)CO(3) by electrochemically splitting Fe(2)O(3) using a cost affordable inert anode[J]. Electrochemistry Communications,2011,13(12):1521-1524.
APA H. Y. Yin,D. Y. Tang,H. Zhu,Y. Zhang,&D. H. Wang.(2011).Production of iron and oxygen in molten K(2)CO(3)-Na(2)CO(3) by electrochemically splitting Fe(2)O(3) using a cost affordable inert anode.Electrochemistry Communications,13(12),1521-1524.
MLA H. Y. Yin,et al."Production of iron and oxygen in molten K(2)CO(3)-Na(2)CO(3) by electrochemically splitting Fe(2)O(3) using a cost affordable inert anode".Electrochemistry Communications 13.12(2011):1521-1524.

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来源:金属研究所

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