Crystallization kinetics and dielectric properties of barium strontium titanate based glass-ceramics
文献类型:期刊论文
作者 | J. C. Chen ; Y. Zhang ; C. S. Deng ; X. M. Dai |
刊名 | Materials Chemistry and Physics
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出版日期 | 2010 |
卷号 | 121期号:1-2页码:109-113 |
关键词 | Glasses Crystallization Differential scanning calorimetry (DSC) Dielectric properties Microstructure borosilicate glass phase-change microstructure behavior system liquids |
ISSN号 | 0254-0584 |
中文摘要 | The crystallization kinetics in the glass system BaxSr(1-x)TiO(3)-Al(2)O(3)-SiO(2) prepared via the conventional melt-quenching technique has been studied by isothermal method using differential scanning calorimetry (DSC). X-ray powder diffraction studies carried out on heat-treated (850-1100 degrees C) glasses reveal the evolution of BaxSr(1-x)TiO(3) crystalline phase along with a second phase of BaAl(2)Si(2)O(8). The exponent n in the Johnson-Mehl-Avrami (JMA) equation applied to the isothermal process is in the range of 2.3-2.73. The apparent activation energy for Ba(x)Sr(1-x)TiO(3) crystal growth obtained from JMA equation under isothermal condition is 457 kJ mol(-1), which is close to the dissociation energy of Si-O bonds. Moreover, there is no remarkably different effect between one-stage and two-stage heat treatment procedures on the microstructures and dielectric properties of barium strontium titanate based glass-ceramics in the present study, according to structure-property analysis. (C) 2010 Elsevier B.V. All rights reserved. |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://210.72.142.130/handle/321006/31025] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | J. C. Chen,Y. Zhang,C. S. Deng,et al. Crystallization kinetics and dielectric properties of barium strontium titanate based glass-ceramics[J]. Materials Chemistry and Physics,2010,121(1-2):109-113. |
APA | J. C. Chen,Y. Zhang,C. S. Deng,&X. M. Dai.(2010).Crystallization kinetics and dielectric properties of barium strontium titanate based glass-ceramics.Materials Chemistry and Physics,121(1-2),109-113. |
MLA | J. C. Chen,et al."Crystallization kinetics and dielectric properties of barium strontium titanate based glass-ceramics".Materials Chemistry and Physics 121.1-2(2010):109-113. |
入库方式: OAI收割
来源:金属研究所
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