Spin-Hamiltonian parameters and local lattice structure for Pd(I) center in gamma-irradiated bis(acetylacetonato)palladium(II)
文献类型：期刊论文
| 作者 | W. L. Feng ; T. X. Zeng ; T. H. Chen ; J. J. Chen |
| 刊名 | Crystal Research and Technology
 |
| 出版日期 | 2010 |
| 卷号 | 45期号:1页码:75-78 |
| 关键词 | crystal-field ligand-field spin-Hamiltonian parameters local lattice structure Pd(I) ion atomic screening constants scf functions crystal resonance ions |
| ISSN号 | 0232-1300 |
| 中文摘要 | This paper reports on a theoretical analysis of spin-Hamiltonian parameters and local lattice structure for Pd(I) center in gamma-irradiated Pd(II)(acac)(2). Through the crystal- and ligand-field theory, the microscopic spin-Hamiltonian parameters and local molecular structure for Pd(I) center in the gamma-irradiated Pd(II)(acac)2 System have been studied by using the high-order perturbation formulas and Newman's superposition model. Based on these calculations, it was found that the distance of the metal-ligand bonds in the square planar complex for Pd(I) center in the gamma-irradiated Pd(II)(acac)(2) system increases by 0.1 angstrom. To understand the detailed physical and chemical properties of the [Pd(I)(acac)(2)](2-) complex, the contributions of the spin-orbit coupling of ligand to spin-Hamiltonian parameters for Pd(I) ion are considered. The theoretical results are in reasonable agreement with the experimental values. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/31105]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | W. L. Feng,T. X. Zeng,T. H. Chen,et al. Spin-Hamiltonian parameters and local lattice structure for Pd(I) center in gamma-irradiated bis(acetylacetonato)palladium(II)[J]. Crystal Research and Technology,2010,45(1):75-78. |
| APA | W. L. Feng,T. X. Zeng,T. H. Chen,&J. J. Chen.(2010).Spin-Hamiltonian parameters and local lattice structure for Pd(I) center in gamma-irradiated bis(acetylacetonato)palladium(II).Crystal Research and Technology,45(1),75-78. |
| MLA | W. L. Feng,et al."Spin-Hamiltonian parameters and local lattice structure for Pd(I) center in gamma-irradiated bis(acetylacetonato)palladium(II)".Crystal Research and Technology 45.1(2010):75-78. |
入库方式： OAI收割
来源：金属研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。