Theoretical Studies of Optical Spectra and EPR Parameters for V4+Impurity Ions in CoMTH
文献类型：期刊论文
| 作者 | J. T. Gong ; L. J. Wang ; W. L. Feng |
| 刊名 | Spectroscopy Letters
 |
| 出版日期 | 2010 |
| 卷号 | 43期号:4页码:306-309 |
| 关键词 | CoMTH crystal field theory EPR optical spectra V4+ spin-hamiltonian parameters crystal-field vanadyl ions absorption glasses |
| ISSN号 | 0038-7010 |
| 中文摘要 | On the basis of the perturbation formulas and 10x10 complete energy matrices for a d1 configuration ion in a tetragonal crystal field, for V4+ ions doped in cobalt maleate tetrahydrate (CoMTH) single crystals, the optical spectra and electron paramagnetic resonance (EPR) parameters (g factors g//, g perpendicular to and hyperfine structure constants A//, A perpendicular to) of the octahedral (VO6)8- clusters have been studied by two theoretical models. By simulating the calculated optical spectra and the EPR parameters to the observed values, the magnitude of orbital reduction factor k, core polarization constant and crystal field parameters [image omitted] are determined. The calculated results are in reasonable agreement with the experimental values. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/31119]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | J. T. Gong,L. J. Wang,W. L. Feng. Theoretical Studies of Optical Spectra and EPR Parameters for V4+Impurity Ions in CoMTH[J]. Spectroscopy Letters,2010,43(4):306-309. |
| APA | J. T. Gong,L. J. Wang,&W. L. Feng.(2010).Theoretical Studies of Optical Spectra and EPR Parameters for V4+Impurity Ions in CoMTH.Spectroscopy Letters,43(4),306-309. |
| MLA | J. T. Gong,et al."Theoretical Studies of Optical Spectra and EPR Parameters for V4+Impurity Ions in CoMTH".Spectroscopy Letters 43.4(2010):306-309. |
入库方式： OAI收割
来源：金属研究所
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