Mechanically Milling with Off-the-Shelf Magnesium Powder to Promote Hydrogen Release from Ammonia Borane
文献类型：期刊论文
| 作者 | J. H. Luo ; X. D. Kang ; P. Wang |
| 刊名 | Journal of Physical Chemistry C
 |
| 出版日期 | 2010 |
| 卷号 | 114期号:23页码:10606-10611 |
| 关键词 | pulsed-laser deposition n-h compounds thermal-decomposition catalyzed dehydrogenation storage material nitride films boron-nitride lithium amidoboranes dissociation |
| ISSN号 | 1932-7447 |
| 中文摘要 | Mechanically milling with the off-the-shelf magnesium (Mg) powder can dramatically improve the dehydrogenation properties of ammonia borane (AB) on all key aspects: enhancing the dehydrogenation kinetics, reducing the induction period, suppressing the formation of volatile byproduct, and alleviating the sample foaming. The postmilled AB/0.5Mg sample can release 8.2 wt % of hydrogen at 100 degrees C within 4 h and deliver >2.5 equiv of hydrogen in AB upon elevating the dehydrogenation temperature to 300 degrees C, giving a material-based hydrogen capacity of 12 wt To. Additionally, the dehydrogenation reaction of the AB/0.5Mg sample becomes significantly less exothermic than that of pristine AB, and remarkably, the third dehydrogenation step is tailored to be endothermic. Combination of phase/structure/chemical state analyses suggest that a considerable amount of Mg participates in the dehydrogenation process, resulting in the formation of Mg-N-B-H product(s). |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/31355]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | J. H. Luo,X. D. Kang,P. Wang. Mechanically Milling with Off-the-Shelf Magnesium Powder to Promote Hydrogen Release from Ammonia Borane[J]. Journal of Physical Chemistry C,2010,114(23):10606-10611. |
| APA | J. H. Luo,X. D. Kang,&P. Wang.(2010).Mechanically Milling with Off-the-Shelf Magnesium Powder to Promote Hydrogen Release from Ammonia Borane.Journal of Physical Chemistry C,114(23),10606-10611. |
| MLA | J. H. Luo,et al."Mechanically Milling with Off-the-Shelf Magnesium Powder to Promote Hydrogen Release from Ammonia Borane".Journal of Physical Chemistry C 114.23(2010):10606-10611. |
入库方式： OAI收割
来源：金属研究所
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