The standard enthalpies of formation of binary intermetallic compounds of some late 4d and 5d transition metals by high temperature direct synthesis calorimetry
文献类型：期刊论文
| 作者 | S. V. Meschel ; P. Nash ; X. Q. Chen |
| 刊名 | Journal of Alloys and Compounds
 |
| 出版日期 | 2010 |
| 卷号 | 492期号:1-2页码:105-115 |
| 关键词 | Transition metal alloys Thermodynamics Enthalpies total-energy calculations wave basis-set ab-initio thermodynamic properties intermediate phases systems feti laves phases nb-rh alloys cobalt |
| ISSN号 | 0925-8388 |
| 中文摘要 | The standard enthalpies of formation of intermetallic compounds of some late 4d and 5d transition metals have been measured by high temperature, direct synthesis calorimetry at 1373 +/- 2 K. The following results in kJ/mol of atoms are reported: NbMn(2) (-10.4 +/- 2.7); NbRu (-0.7 +/- 2.8); RhMo (-4.8 +/- 1.8): PdMn (-45.2 +/- 2.2); Pd(2)Mo (-9.2 +/- 1.9); TaMn(2) (-14.5 +/- 2.5); IrMn(3) (-13.2 +/- 2.8): Pt(3)Cr (-8.8 +/- 3.1); PtMn (-53.6 +/- 1.5); PtMo (-17.9 +/- 2.2); Pt(3)Ta (-21.1 +/- 2.4); and YMn(2) (-2.8 +/- 2.8). The values are compared with predicted values of Miedema and co-workers and with new results from ab initio calculations when available. We will present a systematic picture of how the enthalpies of formation may be related to the atomic number of the transition metal. We will also compare the thermochemical behavior of the Fe, Co, Ni group with the late transition metal alloys. (C) 2009 Elsevier B.V. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/31383]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | S. V. Meschel,P. Nash,X. Q. Chen. The standard enthalpies of formation of binary intermetallic compounds of some late 4d and 5d transition metals by high temperature direct synthesis calorimetry[J]. Journal of Alloys and Compounds,2010,492(1-2):105-115. |
| APA | S. V. Meschel,P. Nash,&X. Q. Chen.(2010).The standard enthalpies of formation of binary intermetallic compounds of some late 4d and 5d transition metals by high temperature direct synthesis calorimetry.Journal of Alloys and Compounds,492(1-2),105-115. |
| MLA | S. V. Meschel,et al."The standard enthalpies of formation of binary intermetallic compounds of some late 4d and 5d transition metals by high temperature direct synthesis calorimetry".Journal of Alloys and Compounds 492.1-2(2010):105-115. |
入库方式： OAI收割
来源：金属研究所
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