Comparative study of EPR spectra and crystal field effect on local structure for (NiF(6))(4-) coordination complex in Ni(2+):ZnF(2), NiF(2), and Ni(2+):MgF(2) systems
文献类型：期刊论文
| 作者 | S. J. Wang ; X. Y. Kuang ; M. L. Duan ; C. X. Zhang ; C. Lu |
| 刊名 | Physica Status Solidi B-Basic Solid State Physics
 |
| 出版日期 | 2010 |
| 卷号 | 247期号:2页码:416-421 |
| 关键词 | paramagnetic-resonance temperature-dependence ground-state mn2+ mgf2 ions kznf3 phase znf2 ni2 |
| ISSN号 | 0370-1972 |
| 中文摘要 | The present work employs the complete energy matrices for a d(8) configuration ion in a D(2h) symmetry ligand field at first time to study the relationship between electron paramagnetic resonance (EPR) spectra and local structure of (NiF(6))(4-) coordination complex in Ni(2+):ZnF(2), NiF(2), and Ni(2+):MgF(2) systems, respectively. The crystal field effect on the local structure of the three systems is investigated contrastively by calculating the values of vertical bar partial derivative D'/partial derivative theta vertical bar and vertical bar partial derivative E'/partial derivative theta vertical bar around the (NiF(6))(4-) coordination complex. Moreover, the theoretical values of the g factors of Ni(2+):ZnF(2), NiF(2), and Ni(2+):MgF(2) systems are reported. Simultaneously, the calculated energy levels are in good agreement with the experimental absorption spectra. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/31514]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | S. J. Wang,X. Y. Kuang,M. L. Duan,et al. Comparative study of EPR spectra and crystal field effect on local structure for (NiF(6))(4-) coordination complex in Ni(2+):ZnF(2), NiF(2), and Ni(2+):MgF(2) systems[J]. Physica Status Solidi B-Basic Solid State Physics,2010,247(2):416-421. |
| APA | S. J. Wang,X. Y. Kuang,M. L. Duan,C. X. Zhang,&C. Lu.(2010).Comparative study of EPR spectra and crystal field effect on local structure for (NiF(6))(4-) coordination complex in Ni(2+):ZnF(2), NiF(2), and Ni(2+):MgF(2) systems.Physica Status Solidi B-Basic Solid State Physics,247(2),416-421. |
| MLA | S. J. Wang,et al."Comparative study of EPR spectra and crystal field effect on local structure for (NiF(6))(4-) coordination complex in Ni(2+):ZnF(2), NiF(2), and Ni(2+):MgF(2) systems".Physica Status Solidi B-Basic Solid State Physics 247.2(2010):416-421. |
入库方式： OAI收割
来源：金属研究所
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