Fabrication and characterization of Pd/Nb(40)Ti(30)Ni(30)/Pd/porous nickel support composite membrane for hydrogen separation and purification
文献类型：期刊论文
| 作者 | L. Y. Xiong ; S. Liu ; L. J. Rong |
| 刊名 | International Journal of Hydrogen Energy
 |
| 出版日期 | 2010 |
| 卷号 | 35期号:4页码:1643-1649 |
| 关键词 | Porous nickel support Magnetron sputtering Composite membrane Amorphous Hydrogen permeation Solid-state diffusion ti-ni alloys permeation characteristics palladium microstructures permeability transport tantalum niobium model glass |
| ISSN号 | 0360-3199 |
| 中文摘要 | A porous nickel support was successfully prepared by uniaxial compression of nickel powders. Microstructures and mechanical properties of Nb(40)Ti(30)Ni(30) membranes fabricated by magnetron sputtering were investigated. Deposited and annealed Nb(40)Ti(30)Ni(30) membranes consisted of amorphous and crystalline phases, respectively. Higher base temperature was shown to increase the hardness and elastic modulus of the Nb(40)Ti(30)Ni(30) membrane, Pd/Nb(40)Ti(30)Ni(30)/Pd/porous nickel support composite membranes were then fabricated using a multilayer magnetron sputtering method. The hydrogen permeability of the composite membranes with amorphous and crystallized Nb(40)Ti(30)Ni(30) metal layer was measured and compared with that of self-supported Nb(40)Ti(30)Ni(30) and Pd alloys. Solid-state diffusion was shown to be the rate-controlling factor when the thickness of the Nb(40)Ti(30)Ni(30) layer was about 12 pm or greater, while other factors were in effect for thinner layers (such as 6 pm). The Pd/Nb(40)Ti(30)Ni(30)/Pd/porous nickel support composite membrane exhibited excellent permeation capability and satisfactory mechanical properties. It is a promising new permeation membrane that could replace Pd and PdAg alloys for hydrogen separation and purification. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/31605]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | L. Y. Xiong,S. Liu,L. J. Rong. Fabrication and characterization of Pd/Nb(40)Ti(30)Ni(30)/Pd/porous nickel support composite membrane for hydrogen separation and purification[J]. International Journal of Hydrogen Energy,2010,35(4):1643-1649. |
| APA | L. Y. Xiong,S. Liu,&L. J. Rong.(2010).Fabrication and characterization of Pd/Nb(40)Ti(30)Ni(30)/Pd/porous nickel support composite membrane for hydrogen separation and purification.International Journal of Hydrogen Energy,35(4),1643-1649. |
| MLA | L. Y. Xiong,et al."Fabrication and characterization of Pd/Nb(40)Ti(30)Ni(30)/Pd/porous nickel support composite membrane for hydrogen separation and purification".International Journal of Hydrogen Energy 35.4(2010):1643-1649. |
入库方式： OAI收割
来源：金属研究所
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