Spin-Hamiltonian parameters for Dy(3+) ion at the trigonal 12-fold coordinated La(3+) site of La(2)Mg(3)(NO(3))(12)center dot 24H(2)O
文献类型:期刊论文
作者 | W. Q. Yang ; W. C. Zheng ; H. G. Liu |
刊名 | Crystal Research and Technology
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出版日期 | 2010 |
卷号 | 45期号:8页码:863-866 |
关键词 | electron paramagnetic resonance crystal-field theory spin-Hamiltonian parameters Dy(3+) La(2)Mg(3)(NO(3))(12)center dot 24H(2)O superposition model analysis electron-paramagnetic-resonance magnesium double nitrate single-crystals field la2mg3(no3)12.24h2o epr |
ISSN号 | 0232-1300 |
中文摘要 | The spin-Hamiltonian parameters (g factors g(parallel to), g(perpendicular to) and hyperfine structure constants (161)A(parallel to), (161)A(perpendicular to), (163)A(parallel to), (163)A(perpendicular to)) for (161)Dy(3+) and (163)Dy(3+) isotopes in the trigonal 12-fold coordinated La(3+) site of La(2)Mg(3)(NO(3))(12)center dot 24H(2)O crystal are calculated from a diagonalization (of energy matrix) method. In the method, the Zeeman and hyperfine interaction terms are added to the conventional Hamiltonian used in the studies of crystal-field energy levels, and a 66x66 energy matrix concerning the ground multiplet (6)H(15/2) and the first to fifth excited multiplets (6)H(13/2), (6)H(11/2), (6)H(9/2), (6)H(7/2) and (6)H(5/2) are applied. The calculated results are discussed. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
原文出处 | |
公开日期 | 2012-04-13 |
源URL | [http://210.72.142.130/handle/321006/31641] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | W. Q. Yang,W. C. Zheng,H. G. Liu. Spin-Hamiltonian parameters for Dy(3+) ion at the trigonal 12-fold coordinated La(3+) site of La(2)Mg(3)(NO(3))(12)center dot 24H(2)O[J]. Crystal Research and Technology,2010,45(8):863-866. |
APA | W. Q. Yang,W. C. Zheng,&H. G. Liu.(2010).Spin-Hamiltonian parameters for Dy(3+) ion at the trigonal 12-fold coordinated La(3+) site of La(2)Mg(3)(NO(3))(12)center dot 24H(2)O.Crystal Research and Technology,45(8),863-866. |
MLA | W. Q. Yang,et al."Spin-Hamiltonian parameters for Dy(3+) ion at the trigonal 12-fold coordinated La(3+) site of La(2)Mg(3)(NO(3))(12)center dot 24H(2)O".Crystal Research and Technology 45.8(2010):863-866. |
入库方式: OAI收割
来源:金属研究所
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