A theoretical study of EPR g factors for the rhombic CuCl(6)(4-) clusters in (3-chloroanilinium)(8) CdCl(6) Cl(4):Cu(2+) crystal
文献类型：期刊论文
| 作者 | D. T. Zhang ; L. He ; W. Q. Yang ; W. C. Zheng |
| 刊名 | Physica B-Condensed Matter
 |
| 出版日期 | 2010 |
| 卷号 | 405期号:17页码:3642-3644 |
| 关键词 | Electron paramagnetic resonance Crystal and ligand field theory Optical spectrum (3-chloroanilinium)(8)[CdCl(6)]Cl(4):Cu(2+) atomic screening constants gyromagnetic factor single-crystals scf functions cu2+ ion parameters distortion resonance spectra vo2+ |
| ISSN号 | 0921-4526 |
| 中文摘要 | In this paper, the third-order perturbation formulas of EPR g factors g(i) (i=x, y, z) for d(9) ions in rhombic symmetry where the ground state being an vertical bar d(x2-y2)> admixture of and vertical bar d(z2)> states are derived. These formulas are based on a two-spin-orbit-parameter model in which the contributions to g factors due to both the spin-orbit parameter of the central 3d(n) ion and that of ligand ion are included. From these formulas, the g factors g(i) for the rhombic CuCl(6)(4-) clusters in (3-chloroanilinium)(8)[CdCl(6)]CL(4):Cu(2+) crystal are calculated. The calculated values are in good agreement with those obtained by the complete diagonalization (of energy matrix) method and experimental values. Results are discussed. (C) 2010 Elsevier B.V. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2012-04-13 |
| 源URL | [http://210.72.142.130/handle/321006/31683]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | D. T. Zhang,L. He,W. Q. Yang,et al. A theoretical study of EPR g factors for the rhombic CuCl(6)(4-) clusters in (3-chloroanilinium)(8) CdCl(6) Cl(4):Cu(2+) crystal[J]. Physica B-Condensed Matter,2010,405(17):3642-3644. |
| APA | D. T. Zhang,L. He,W. Q. Yang,&W. C. Zheng.(2010).A theoretical study of EPR g factors for the rhombic CuCl(6)(4-) clusters in (3-chloroanilinium)(8) CdCl(6) Cl(4):Cu(2+) crystal.Physica B-Condensed Matter,405(17),3642-3644. |
| MLA | D. T. Zhang,et al."A theoretical study of EPR g factors for the rhombic CuCl(6)(4-) clusters in (3-chloroanilinium)(8) CdCl(6) Cl(4):Cu(2+) crystal".Physica B-Condensed Matter 405.17(2010):3642-3644. |
入库方式： OAI收割
来源：金属研究所
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